Eco-Friendly Synthesis of Gold Nanoparticles through Gracilaria sp Seaweed Extract for Foam Height Stability in Liquid Hand Soap Formulations

Iwan Syahjoko Saputra, Anjar Hermadi Saputro, N. Adliani, Dwinna Rahmi, S. Sudirman, Yogi Nopiandi
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Abstract

Gold nanoparticles (G-NPs) were successfully synthesized using Gracilaria sp seaweed extract. Visually, color changes from purple-blue to ruby red and then finally to pink. UV-Vis spectrophotometer showed the optimum condition of G-NPs at 531 nm wavelength with an absorbance value of 1.1. The fourier transform infrared (FTIR) spectroscopy shows the absorption peak of functional groups at the Gracilaria sp seaweed extract like hydroxyl group (-OH), aromatic (C=C), alkane (C-H), and amine (C-N) at the wavenumbers of 3356, 1613, 1456, and 1182 cm-1, respectively. The X-ray diffraction (XRD) shows the crystallinity peaks of G-NPs at 2θ: 38.3o, 44.1o, 64.8o, and 77.8o with miller indices of (111), (200), (220), and (311). The Particle size analyzer (PSA) shows the distribution and particle size average of G-NPs was 11.8 nm. Analysis of particle zeta charge (PZC) confirms the total charge of inter-particles was -24.7 mV. The transmission electron microscopy (TEM) images shows the G-NPs was spherical shape with a particle size was 20 nm. The hand soap@G-NPs have a pH of 6.0 and foam height stability of 4.1 cm for 10 min.
用紫菜提取物合成金纳米颗粒的生态友好型研究,以提高洗手液配方中的泡沫高度稳定性
以紫菜提取物为原料成功合成了金纳米颗粒(g - np)。视觉上,颜色从紫蓝色变成宝石红色,最后变成粉红色。紫外可见分光光度计测定G-NPs的最佳条件为531 nm,吸光度值为1.1。傅里叶变换红外光谱(FTIR)显示了紫菜提取物中羟基(-OH)、芳香(C=C)、烷烃(C- h)和胺(C- n)等官能团在3356、1613、1456和1182 cm-1波数处的吸收峰。x射线衍射(XRD)结果表明,G-NPs的结晶度峰位于2θ: 38.30、44.10、64.80和77.80,米勒指数分别为(111)、(200)、(220)和(311)。粒径分析仪(PSA)显示G-NPs的分布和平均粒径为11.8 nm。粒子zeta电荷(PZC)分析证实粒子间总电荷为-24.7 mV。透射电镜(TEM)显示G-NPs为球形,粒径为20 nm。手soap@G-NPs pH值为6.0,泡沫高度稳定性为4.1 cm,持续10分钟。
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