Research on preparation technology of animal skin intrinsic multifunctional packaging material

IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS
Jiaxing Zhang, Zhongzhen Long, Hui Chen, Z. Shan
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Abstract

High-end leather packaging material safe, environmentally friendly, and has a good market prospect. It is an interesting technology to solve the intrinsic functionalization of skin collagen packaging materials. Nano-Hydroxyapatite (HA) precursors solution with a specific 1.67 calcium to phosphorus ratio (Ca/P) were infiltrated into the three-dimensional collagen network matrix (3DCM) in situ growth based on goat skin pretreated with glutaraldehyde and the HAG-3DCM was obtained. After compression, a transparent film HAG-3DCM-was formed. Structural and functional characterization showed that the HAG-3DCM-CM film has good comprehensive performance, such as the tensile strength increased to 67 mPa from 28 mPa, the bending resistance increased from 5 cycles to 50 cycles and the swelling degree from 55% to 12%. HA disperses and fixes the three-dimensional collagen network matrix (3DCM) fibers, improves its stability against humidity and heat, and the thermal conductivity changed from 0.72 W/(K•m) to 0.65 W/(K•m). HAG-3DCM has a relatively high limiting oxygen index of 26.5%. This study demonstrates a new approach for preparing animal skin packaging materials with new application value.
动物皮本征多功能包装材料的制备工艺研究
高档皮革包装材料安全、环保,具有良好的市场前景。解决皮肤胶原蛋白包装材料的内在功能化是一项有趣的技术。将钙磷比(Ca/P)为1.67的纳米羟基磷灰石(HA)前体溶液浸润到经戊二醛预处理的山羊皮肤原位生长的三维胶原网络基质(3DCM)中,获得HAG-3DCM。压缩后形成透明薄膜hag - 3dcm。结构和功能表征表明,HAG-3DCM-CM薄膜具有良好的综合性能,抗拉强度由28 mPa提高到67 mPa,抗弯性能由5次循环提高到50次循环,膨胀度由55%提高到12%。透明质酸对三维胶原网络基质(3DCM)纤维具有分散和固定作用,提高了其抗湿、抗热稳定性,导热系数由0.72 W/(K•m)提高到0.65 W/(K•m)。HAG-3DCM的极限氧指数较高,为26.5%。本研究为动物皮包装材料的制备提供了一条新的途径,具有新的应用价值。
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来源期刊
Journal of Plastic Film & Sheeting
Journal of Plastic Film & Sheeting 工程技术-材料科学:膜
CiteScore
6.00
自引率
16.10%
发文量
33
审稿时长
>12 weeks
期刊介绍: The Journal of Plastic Film and Sheeting improves communication concerning plastic film and sheeting with major emphasis on the propogation of knowledge which will serve to advance the science and technology of these products and thus better serve industry and the ultimate consumer. The journal reports on the wide variety of advances that are rapidly taking place in the technology of plastic film and sheeting. This journal is a member of the Committee on Publication Ethics (COPE).
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