Organic Polymer-Constructed Chiral Particles: Preparation and Chiral Applications

IF 11.1 2区化学 Q1 POLYMER SCIENCE

Polymer Reviews Pub Date : 2022-01-31 DOI:10.1080/15583724.2022.2033764

Haizheng Zhong, Jianping Deng

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引用次数: 6

Abstract

Abstract Chirality and chiral structures are ubiquitous in nature, and play vital and essential roles in organisms. Polymer particles have attracted substantial interest because of their wide and significant practical applications. Combining fascinating chirality and the advantages of polymer particles in one entity will open up a great number of advanced functional chiral particles. In spite of the great advancements made in this field, there are only a few review articles summarizing the studies dealing with the research subject. Thus, the present article summarizes the latest progress made in the field, especially the literature published from 2018 to 2021. This review first summarizes the preparation methods toward organic polymer chiral particles (OPCPs), including precipitation polymerization, emulsion polymerization, dispersion polymerization, suspension polymerization, post chiralization, self-assembly, and others. Typical applications of the chiral polymer particles in research fields associated with chirality are introduced, ranging from asymmetric catalysis, chromatographic separation, enantioselective crystallization, enantioselective adsorption to drug release. The existing challenges in OPCPs are presented; and future perspectives in the related research fields are also proposed.

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有机聚合物构建的手性颗粒:制备和手性应用

手性和手性结构在自然界中无处不在，在生物体中起着至关重要的作用。聚合物颗粒因其广泛而重要的实际应用而引起了人们的极大兴趣。将高分子粒子迷人的手性与高分子粒子的优点结合在一起，将开辟出大量的高级功能手性粒子。尽管这一领域取得了很大的进步，但只有少数几篇综述性文章概述了涉及该研究主题的研究。因此，本文总结了该领域的最新进展，特别是2018年至2021年发表的文献。本文首先综述了有机聚合物手性颗粒(OPCPs)的制备方法，包括沉淀聚合、乳液聚合、分散聚合、悬浮聚合、后手性化、自组装等。介绍了手性聚合物颗粒在与手性相关的研究领域的典型应用，包括不对称催化、色谱分离、对映选择结晶、对映选择吸附、药物释放等。提出了opcp存在的挑战;并对今后的研究方向进行了展望。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Polymer Reviews 工程技术-高分子科学

CiteScore

24.80

自引率

0.80%

发文量

审稿时长

6 months

期刊介绍： Polymer Reviews is a reputable publication that focuses on timely issues within the field of macromolecular science and engineering. The journal features high-quality reviews that have been specifically curated by experts in the field. Topics of particular importance include biomedical applications, organic electronics and photonics, nanostructures, micro- and nano-fabrication, biological molecules (such as DNA, proteins, and carbohydrates), polymers for renewable energy and environmental applications, and interdisciplinary intersections involving polymers. The articles in Polymer Reviews fall into two main categories. Some articles offer comprehensive and expansive overviews of a particular subject, while others zero in on the author's own research and situate it within the broader scientific landscape. In both types of articles, the aim is to provide readers with valuable insights and advancements in the field of macromolecular science and engineering.