Sorption and diffusion of oxygen and nitrogen in molecular sieve RS-10

S. Farooq
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引用次数: 19

Abstract

Henry's law constants and intracrystalline diffusivities of oxygen and nitrogen in molecular sieve RS-10 have been measured by the pulse chromatographic method. Both moment analysis and time domain fitting of the experimental response curves give consistent results. Heats of adsorption and activation energies have been determined from the equilibrium and kinetic measurements carried out at different temperatures.

RS-10分子筛中氧、氮的吸附与扩散
用脉冲色谱法测定了RS-10分子筛中氧和氮的亨利定律常数和晶内扩散系数。试验响应曲线的矩分析和时域拟合结果一致。通过在不同温度下进行的平衡和动力学测量,确定了吸附热和活化能。
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