{"title":"Scanning Electron Microscopy and Kinetic Studies of Ketene-Acetylated Wood/Cellulose High-Density Polyethylene Blends","authors":"Y. Azeh, G. Olatunji, P. Mamza","doi":"10.1155/2012/456491","DOIUrl":null,"url":null,"abstract":"Acetylated cellulose and wood cellulose as well as untreated cellulose polyethylene blends were subjected to kinetic studies using water, 0.5 M NaOH, and 0.5 M HCl solutions in order to investigate their absorbent properties at 0.5/1.0 cellulose/wood cellulose/polyethylene matrix. The results of the absorption studies showed that the untreated cellulose and wood cellulose blends absorbed water and the acid and alkali solutions higher than the treated samples, which showed a reduction in acid, alkali, and water uptake. In this work, the effects of acetylation on the morphological studies of the polyethylene blends were obvious. The presence of acetyl groups improved the interfacial bonding between the polymer matrix and cellulose as well as the wood cellulose fibers, as evidenced by scanning electron microscopy (SEM).","PeriodicalId":13788,"journal":{"name":"International Journal of Carbohydrate Chemistry","volume":"161 1","pages":"1-7"},"PeriodicalIF":0.0000,"publicationDate":"2012-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"14","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Carbohydrate Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2012/456491","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 14
Abstract
Acetylated cellulose and wood cellulose as well as untreated cellulose polyethylene blends were subjected to kinetic studies using water, 0.5 M NaOH, and 0.5 M HCl solutions in order to investigate their absorbent properties at 0.5/1.0 cellulose/wood cellulose/polyethylene matrix. The results of the absorption studies showed that the untreated cellulose and wood cellulose blends absorbed water and the acid and alkali solutions higher than the treated samples, which showed a reduction in acid, alkali, and water uptake. In this work, the effects of acetylation on the morphological studies of the polyethylene blends were obvious. The presence of acetyl groups improved the interfacial bonding between the polymer matrix and cellulose as well as the wood cellulose fibers, as evidenced by scanning electron microscopy (SEM).
采用水、0.5 M NaOH和0.5 M HCl溶液对乙酰化纤维素和木纤维素以及未经处理的纤维素聚乙烯共混物进行了动力学研究,以考察它们在0.5/1.0纤维素/木纤维素/聚乙烯基体中的吸收性能。吸附研究结果表明,未经处理的纤维素和木纤维素共混物对水和酸碱溶液的吸收率高于处理后的样品,表明其对酸、碱和水的吸收率降低。在这项工作中,乙酰化对聚乙烯共混物的形态研究的影响是明显的。扫描电镜(SEM)结果表明,乙酰基的存在改善了聚合物基体与纤维素以及木质纤维素纤维之间的界面键合。