pH Dependence of Cyanogen Potentials of Local Wines (Buruku and Pito) Using Cyanomethemoglobin Complex

Osuegba, O.S., Adeleke-Ajagbe, V. O., A. B. O
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Abstract

The cyanogen potentials of local wines (burukutu, pito,) and the effect of pH (5.6-9.0) on the samples was determined using cyanomethemoglobin complex method. A total of 108 test samples were analyzed and the hydrogen cyanide content was found to vary considerably from 0.0313±0.0052 mg/L to 0.2444±0.0010 mg/L. pito was found to have the highest cyanogen potential with mean concentration of 0.2444±0.0010 mg/L at pH of 8.4 and burukutu found to have the lowest cyanogen potential with mean concentration of 0.0313±0.0052 mg/L at pH of 8.2. The highest mean concentration of cyanogen potential found in this study (0.2444±0.0010 mg/L) is lower than the recommended WHO and ISO standard (10mg/kg; 0.5-3.5 mg/kg body weight) and thus the samples may be consumed without the risk of cyanide poisoning.
利用蓝高铁血红蛋白复合物研究当地葡萄酒(布鲁库和皮托)氰化电位的pH依赖性
采用氰高铁血红蛋白络合物法测定了当地葡萄酒(布鲁库图、皮托、)的氰电位及pH(5.6 ~ 9.0)对样品的影响。共分析了108个测试样品,发现氰化氢含量在0.0313±0.0052 mg/L至0.2444±0.0010 mg/L之间变化很大。在pH为8.4时,皮托的氰电位最高,平均浓度为0.2444±0.0010 mg/L;在pH为8.2时,布鲁库图的氰电位最低,平均浓度为0.0313±0.0052 mg/L。本研究发现的最高平均氰势浓度(0.2444±0.0010 mg/L)低于WHO和ISO推荐标准(10mg/kg;0.5-3.5毫克/公斤体重),因此食用这些样本不会有氰化物中毒的风险。
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