Spectral, lifetime and photochemical characteristics of 4-acetoxy-chalcone in viscous media

Abstract

Both fluorescence and excitation spectra of 4-acetoxy-chalcone (4-AC) are bathochromically shifted as the medium polarity increases. The fluorescence quantum yields are sensitive to medium viscosity and increase sharply as the medium viscosity increases due to prohibition of radiationless deactivation pathways. The fluorescence lifetime of 4-AC in glycerol has been measured as τ = 1.9 ns. The photochemical quantum yields (thought to be a trans-cis photo-isomerization) are also sensitive to medium viscosity with minimum φ_c values obtained in highly viscous solvents. The effect of medium viscosity on the quenching of 4-AC fluorescence using picric acid as a quencher has been studied. A static-type quenching mechanism is proposed to account for the quenching efficiency as the medium viscosity increases.