CHAPTER 6. Onium Ion-assisted Organic Reactions Through Cation–π Interactions

S. Yamada
{"title":"CHAPTER 6. Onium Ion-assisted Organic Reactions Through Cation–π Interactions","authors":"S. Yamada","doi":"10.1039/9781788016490-00137","DOIUrl":null,"url":null,"abstract":"The cation–π interaction is an attractive noncovalent interaction between a cation and a π-face. Owing to the stronger interaction energy than those of the other π interactions, such as π–π and CH–π interactions, the cation–π interaction has recently been recognized as a new tool for controlling the regio- and stereoselectivities in various types of organic reactions. This chapter attempts to cover a variety of organic reactions assisted by interactions between unreactive onium ions and π-faces, which will provide comprehensive knowledge on the role of cation–π interactions in organic synthesis.","PeriodicalId":10054,"journal":{"name":"Catalysis Series","volume":"45 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Series","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/9781788016490-00137","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1

Abstract

The cation–π interaction is an attractive noncovalent interaction between a cation and a π-face. Owing to the stronger interaction energy than those of the other π interactions, such as π–π and CH–π interactions, the cation–π interaction has recently been recognized as a new tool for controlling the regio- and stereoselectivities in various types of organic reactions. This chapter attempts to cover a variety of organic reactions assisted by interactions between unreactive onium ions and π-faces, which will provide comprehensive knowledge on the role of cation–π interactions in organic synthesis.
第六章。通过阳离子-π相互作用的铵离子辅助有机反应
阳离子-π相互作用是阳离子和π面之间具有吸引力的非共价相互作用。由于阳离子- π相互作用比其他π相互作用(如π - π和CH - π)具有更强的相互作用能,阳离子- π相互作用最近被认为是控制各种类型有机反应的区域选择性和立体选择性的新工具。本章试图涵盖各种由非反应性离子和π面相互作用辅助的有机反应,这将提供有关阳离子-π相互作用在有机合成中的作用的全面知识。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信