P. Magnus, L. Diorazio, T. Donohoe, M. Giles, P. Pye, James G. Tarrant, S. Thom
{"title":"New strategy for the synthesis of the taxane diterpenes: formation of the eight-membered B-ring of taxol by semi-pinacol rearrangement","authors":"P. Magnus, L. Diorazio, T. Donohoe, M. Giles, P. Pye, James G. Tarrant, S. Thom","doi":"10.1039/C39950001935","DOIUrl":null,"url":null,"abstract":"Solvolysis of the neopentyl triflates 14, 25 and 32 resulted in ring expansion of a seven-membered ring into the eight-membered ring required for the synthesis of the taxanes diterpenoids.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"92 1","pages":"1935-1936"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001935","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
Solvolysis of the neopentyl triflates 14, 25 and 32 resulted in ring expansion of a seven-membered ring into the eight-membered ring required for the synthesis of the taxanes diterpenoids.