Development of Epoxy-polyester Nanocomposite Materials with Improved Physical and Mechanical Properties for Increasing Transport Vehicle Reliability

M. Brailo, A. Buketov, S. Yakushchenko, O. Sapronov, D. Dmytriiev, N. Buketova
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Abstract

The significant attention is paid to the development of new composite materials which can be widely used in the manufacturing and repairing details and their components in different branches of industry including water transport. Intensity of cargo transportation by the water transport, an increase in the frequency of loading operations, their operation under the influence of aggressive environments put forward requirements for the improvement of indicators of resource saving of vehicle units and increasing the inter-resource period of work. In this context, the epoxy composite materials are one of the most promising materials, which meet the requirements of modern transport industry, due to their performance characteristics, which in most cases are better than traditional metals and alloys. Therefore, in the work, the physical and mechanical properties of composite materials with nanodispersed additives based on the epoxy-polyester matrix, were studied. An oxidized nanoparticle additive and pyrogenic silicon dioxide were used as fillers. It was found that epoxy-polyester composites are characterized by improved properties at significant amount of the oxidized nanoparticle additive. An optimal ratio of the epoxy-polyester binder and additive was 100:0.06-0.08 pts. wt. It was ascertained that the introduction of pyrogenic silicon dioxide leads to a decrease in values of investigated properties of composite materials. In particular, the fracture surface of epoxy-polyester materials was analyzed with the method of optical microscopy. It was stated that composite materials filled with pyrogenic silicon dioxide were characterized by high residual stresses. The presence of low amount of fracture lines on the surface of composite materials filled with nanodispersed additive was revealed. Therefore, composite materials with nanofiller are characterized by higher resistance for fracture and impact loads.
提高交通工具可靠性的环氧-聚酯纳米复合材料的研究
新型复合材料的开发备受关注,可广泛应用于包括水运在内的不同工业部门的零件及其部件的制造和修理。水运货物运输强度增大,装货作业频次增加,其作业受恶劣环境影响,对车辆单元资源节约指标的提高和资源间工作周期的增加提出了要求。在此背景下,环氧复合材料因其在大多数情况下优于传统金属和合金的性能特点而成为满足现代运输工业要求的最有前途的材料之一。因此,在工作中,研究了基于环氧-聚酯基体的纳米分散添加剂复合材料的物理力学性能。采用氧化纳米颗粒添加剂和热原二氧化硅作为填料。结果表明,加入一定量的氧化纳米颗粒后,环氧-聚酯复合材料的性能得到改善。环氧聚酯粘结剂与添加剂的最佳配比为100:0.06-0.08 pts。确定了热原二氧化硅的引入会导致复合材料所研究的性能值下降。特别是用光学显微镜的方法对环氧聚酯材料的断裂面进行了分析。指出了以热原二氧化硅填充的复合材料具有高残余应力的特点。结果表明,纳米分散添加剂填充的复合材料表面出现少量断口。因此,添加纳米填料的复合材料具有更高的抗断裂和抗冲击性能。
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