Reduction of the substitutional disorder by heat treatments in Mn2-xCoxVAl Heusler alloys

D. Benea, R. Gavrea, M. Coldea, L. Barbu-Tudoran, O. Isnard, V. Pop
{"title":"Reduction of the substitutional disorder by heat treatments in Mn2-xCoxVAl Heusler alloys","authors":"D. Benea, R. Gavrea, M. Coldea, L. Barbu-Tudoran, O. Isnard, V. Pop","doi":"10.21741/9781945291999-25","DOIUrl":null,"url":null,"abstract":"We report on the preparation and the atomic disorder reduction by annealing in Mn2xCoxVAl Heusler alloys. The degrees of the B2 and L21 atomic ordering for the as-cast samples, obtained from intensity ratios of (200) and (111) peaks respectively related to (220) peak of the Xray patterns, are significantly improved after annealing at 700 800 °C for 72 h. The diminution of the substitutional disorder is essential in these types of compounds, as the half-metallic character and the magnetic properties are primarily influenced by this factor. Introduction Heusler alloys are ternary intermetallic compounds of the L21 structure with stoichiometric composition X2YZ, where X and Y are usually two different transition metals and Z is a nonmagnetic element [1]. Earlier studies have shown that Mn2VAl Heusler alloy is a half-metallic ferrimagnet [2-5]. This compound is characterized by an antiparallel coupling between the Mn and V magnetic moments, the total spin moment being 2 μB per formula unit [2, 3]. The high Curie temperature of 760 K [3] makes it interesting for spintronic applications. The spin compensation in Mn2−xCoxVAl alloy was induced by progressive substitution of Co for Mn and a fully compensated ferrimagnetic behavior has been experimentally obtained for the MnCoVAl alloy [4]. The presence of a considerable atomic disorder in the Mn2VAl compound due to the intermixing of the V and Al atoms has been reported [5]. Previous studies have shown that the magnetic properties and the half-metallic character of these Heusler alloys are strongly influenced by the crystallographic disorder [1, 3, 6, 7]. The aim of the present work is to reduce the substitutional disorder by heat treatments in Mn2−xCoxVAl Heusler alloys. For the evaluation of the atomic ordering in the full Heusler alloys, the Takamura’s model has been used [8]. In order to determine and to adjust the ordering parameters defined in this model, X-ray diffraction (XRD), differential scanning calorimetry (DSC) and neutron diffraction studies have been performed. Powder Metallurgy and Advanced Materials – RoPM&AM 2017 Materials Research Forum LLC Materials Research Proceedings 8 (2018) 219-227 doi: http://dx.doi.org/10.21741/9781945291999-25 220 Experimental details The Mn2−xCoxVAl (x= 0, 0.2, 0.6, 1) ingots were prepared by induction melting under a purified Ar atmosphere of the starting components Mn (99.95 wt %), Al (99.999 wt %), V (99.99 wt %) and Co (99.99 wt %). An excess of 3 wt % of manganese was added to the stoichiometric mixture in order to compensate for preferential Mn evaporation during the melting processes. The samples were turned and remelted repeatedly in order to ensure homogeneity. The water-cooled copper crucible ensured a rapid cooling of the alloys after melting. The samples were wrapped in tantalum foil, sealed in quartz tubes and subsequently annealed in an Ar atmosphere for 72 hours. The stoichiometry of our as-cast samples was investigated using the energy dispersive X-ray analysis (EDX). The crystal structure of the alloys was investigated at room temperature by using a Brȕker D8 Advance diffractometer using Cu Kα radiation. The structural transformations in the 50 – 1000 °C temperature range were identified from differential scanning calorimetry under Ar atmosphere with a temperature ramp rate of 20 °C/min. The cooling was performed at 20 °C/min controlled by forced air cooling (Q600 TA Instruments). The neutron diffraction investigations have been performed at the Institute Laue-Langevin, Grenoble, France, using the high intensity powder diffractometer D1B [9] exploiting the wavelength of 0.128 nm and 0.252 nm respectively, which were selected by Ge and pyrolytic graphite monochromator respectively. The diffraction patterns were indexed by using the FULLPROF program [10]. Results and discussions The EDX measurements on the as-cast MnCoVAl sample are shown in Fig. 1. The quantity for each element is given in atomic percent which, for ideal MnCoVAl alloy stoichiometry, should be 25 at % for each element. The previous studies showed that 5 wt % excess of Al should be added in order to compensate the weight loss due to the evaporation of Al [11]. Fig. 1. EDX spectrum of the as-cast MnCoVAl alloy. Powder Metallurgy and Advanced Materials – RoPM&AM 2017 Materials Research Forum LLC Materials Research Proceedings 8 (2018) 219-227 doi: http://dx.doi.org/10.21741/9781945291999-25 221 By using no additional Al and by adding 3 wt % Mn, in our samples the weight loss of the final materials is less than 1 wt %. As can be observed in Fig.1, the stoichiometry of our sample is in good agreement with the desired Heusler-type structure, taking into account the measurement errors. The Mn2-xCoxVAl alloys crystallize in an ideal full Heusler (L21) structure (Fig. 2), were the Mn/Co atoms occupy the 8c positions at (1/4 1/4 1/4) and (3/4 3/4 3/4), V occupy the 4a positions at (0 0 0) and Al occupy the 4b positions at (1/2 1/2 1/2) [3]. Fig. 2. X2YZ L21-type crystal structure of Heusler alloys. Fig. 3. Room temperature X-ray diffraction pattern of the as-cast Mn2-xCoxVAl samples. The data are normalized to the intensity of the (220) reflection. Powder Metallurgy and Advanced Materials – RoPM&AM 2017 Materials Research Forum LLC Materials Research Proceedings 8 (2018) 219-227 doi: http://dx.doi.org/10.21741/9781945291999-25 222 The X-ray diffraction patterns at room temperature of the as-cast Mn2−xCoxVAl (x = 0, 0.2, 0.6 and 1) alloys are shown in Fig.3. The XRD patterns prove that the as-cast alloys crystallize in a single phase, corresponding to X2YZ Heusler type structure, cubic space group Fm3�m (spatial group no. 225), where the Mn and Co atoms occupy the 8c Wyckoff sites (X), while V and Al atoms are placed on the 4a (Y) and 4b (Z) crystal site, respectively (see Fig.2.). The (111) and (200) superlattice diffraction lines from the XRD patterns prove that all the Mn2-xCoxVAl alloys exhibit a stable L21 structure of full Heusler alloys. The extinction of the reflection from the (111) plane indicates an intermixing between the V and Al atoms. Also, if all Mn, V and Al atoms get intermixed, both super-latttice reflections (111) and (200) would disappear [1, 4, 8]. We employed the Takamura’s model to investigate the substitutional disorder in our Mn2−xCoxVAl (x = 0, 0.2, 0.6 and 1) alloys. In this model, two types of ordering parameters have been defined to describe the intermixing between the atomic positions. The SB2 order parameter describes the probability of Mn atoms to occupy the X sites (8c) in the X2YZ full Heusler alloys, being defined: SB2 = MMM oM X−MMM oM X rrMror MMM oM X ffff −MMM oM X rrMror (1) The second order parameter SL21 describes the probability of V to occupy the Y position in the X2YZ full Heusler alloys: SL21 = MV oM Y−MV oM Y rrMror MVoM Y ffff −MVoM Y rrMror (2) Table 1. Structural parameters including SB2 and SL21 ordering parameters unit cell constant and the site occupation for the as-cast Mn2−xCoxVAl samples. Co content (x) Atoms X site Y site Z site SB2 SL21 alat (nm)","PeriodicalId":20390,"journal":{"name":"Powder Metallurgy and Advanced Materials","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2018-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Powder Metallurgy and Advanced Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21741/9781945291999-25","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1

Abstract

We report on the preparation and the atomic disorder reduction by annealing in Mn2xCoxVAl Heusler alloys. The degrees of the B2 and L21 atomic ordering for the as-cast samples, obtained from intensity ratios of (200) and (111) peaks respectively related to (220) peak of the Xray patterns, are significantly improved after annealing at 700 800 °C for 72 h. The diminution of the substitutional disorder is essential in these types of compounds, as the half-metallic character and the magnetic properties are primarily influenced by this factor. Introduction Heusler alloys are ternary intermetallic compounds of the L21 structure with stoichiometric composition X2YZ, where X and Y are usually two different transition metals and Z is a nonmagnetic element [1]. Earlier studies have shown that Mn2VAl Heusler alloy is a half-metallic ferrimagnet [2-5]. This compound is characterized by an antiparallel coupling between the Mn and V magnetic moments, the total spin moment being 2 μB per formula unit [2, 3]. The high Curie temperature of 760 K [3] makes it interesting for spintronic applications. The spin compensation in Mn2−xCoxVAl alloy was induced by progressive substitution of Co for Mn and a fully compensated ferrimagnetic behavior has been experimentally obtained for the MnCoVAl alloy [4]. The presence of a considerable atomic disorder in the Mn2VAl compound due to the intermixing of the V and Al atoms has been reported [5]. Previous studies have shown that the magnetic properties and the half-metallic character of these Heusler alloys are strongly influenced by the crystallographic disorder [1, 3, 6, 7]. The aim of the present work is to reduce the substitutional disorder by heat treatments in Mn2−xCoxVAl Heusler alloys. For the evaluation of the atomic ordering in the full Heusler alloys, the Takamura’s model has been used [8]. In order to determine and to adjust the ordering parameters defined in this model, X-ray diffraction (XRD), differential scanning calorimetry (DSC) and neutron diffraction studies have been performed. Powder Metallurgy and Advanced Materials – RoPM&AM 2017 Materials Research Forum LLC Materials Research Proceedings 8 (2018) 219-227 doi: http://dx.doi.org/10.21741/9781945291999-25 220 Experimental details The Mn2−xCoxVAl (x= 0, 0.2, 0.6, 1) ingots were prepared by induction melting under a purified Ar atmosphere of the starting components Mn (99.95 wt %), Al (99.999 wt %), V (99.99 wt %) and Co (99.99 wt %). An excess of 3 wt % of manganese was added to the stoichiometric mixture in order to compensate for preferential Mn evaporation during the melting processes. The samples were turned and remelted repeatedly in order to ensure homogeneity. The water-cooled copper crucible ensured a rapid cooling of the alloys after melting. The samples were wrapped in tantalum foil, sealed in quartz tubes and subsequently annealed in an Ar atmosphere for 72 hours. The stoichiometry of our as-cast samples was investigated using the energy dispersive X-ray analysis (EDX). The crystal structure of the alloys was investigated at room temperature by using a Brȕker D8 Advance diffractometer using Cu Kα radiation. The structural transformations in the 50 – 1000 °C temperature range were identified from differential scanning calorimetry under Ar atmosphere with a temperature ramp rate of 20 °C/min. The cooling was performed at 20 °C/min controlled by forced air cooling (Q600 TA Instruments). The neutron diffraction investigations have been performed at the Institute Laue-Langevin, Grenoble, France, using the high intensity powder diffractometer D1B [9] exploiting the wavelength of 0.128 nm and 0.252 nm respectively, which were selected by Ge and pyrolytic graphite monochromator respectively. The diffraction patterns were indexed by using the FULLPROF program [10]. Results and discussions The EDX measurements on the as-cast MnCoVAl sample are shown in Fig. 1. The quantity for each element is given in atomic percent which, for ideal MnCoVAl alloy stoichiometry, should be 25 at % for each element. The previous studies showed that 5 wt % excess of Al should be added in order to compensate the weight loss due to the evaporation of Al [11]. Fig. 1. EDX spectrum of the as-cast MnCoVAl alloy. Powder Metallurgy and Advanced Materials – RoPM&AM 2017 Materials Research Forum LLC Materials Research Proceedings 8 (2018) 219-227 doi: http://dx.doi.org/10.21741/9781945291999-25 221 By using no additional Al and by adding 3 wt % Mn, in our samples the weight loss of the final materials is less than 1 wt %. As can be observed in Fig.1, the stoichiometry of our sample is in good agreement with the desired Heusler-type structure, taking into account the measurement errors. The Mn2-xCoxVAl alloys crystallize in an ideal full Heusler (L21) structure (Fig. 2), were the Mn/Co atoms occupy the 8c positions at (1/4 1/4 1/4) and (3/4 3/4 3/4), V occupy the 4a positions at (0 0 0) and Al occupy the 4b positions at (1/2 1/2 1/2) [3]. Fig. 2. X2YZ L21-type crystal structure of Heusler alloys. Fig. 3. Room temperature X-ray diffraction pattern of the as-cast Mn2-xCoxVAl samples. The data are normalized to the intensity of the (220) reflection. Powder Metallurgy and Advanced Materials – RoPM&AM 2017 Materials Research Forum LLC Materials Research Proceedings 8 (2018) 219-227 doi: http://dx.doi.org/10.21741/9781945291999-25 222 The X-ray diffraction patterns at room temperature of the as-cast Mn2−xCoxVAl (x = 0, 0.2, 0.6 and 1) alloys are shown in Fig.3. The XRD patterns prove that the as-cast alloys crystallize in a single phase, corresponding to X2YZ Heusler type structure, cubic space group Fm3�m (spatial group no. 225), where the Mn and Co atoms occupy the 8c Wyckoff sites (X), while V and Al atoms are placed on the 4a (Y) and 4b (Z) crystal site, respectively (see Fig.2.). The (111) and (200) superlattice diffraction lines from the XRD patterns prove that all the Mn2-xCoxVAl alloys exhibit a stable L21 structure of full Heusler alloys. The extinction of the reflection from the (111) plane indicates an intermixing between the V and Al atoms. Also, if all Mn, V and Al atoms get intermixed, both super-latttice reflections (111) and (200) would disappear [1, 4, 8]. We employed the Takamura’s model to investigate the substitutional disorder in our Mn2−xCoxVAl (x = 0, 0.2, 0.6 and 1) alloys. In this model, two types of ordering parameters have been defined to describe the intermixing between the atomic positions. The SB2 order parameter describes the probability of Mn atoms to occupy the X sites (8c) in the X2YZ full Heusler alloys, being defined: SB2 = MMM oM X−MMM oM X rrMror MMM oM X ffff −MMM oM X rrMror (1) The second order parameter SL21 describes the probability of V to occupy the Y position in the X2YZ full Heusler alloys: SL21 = MV oM Y−MV oM Y rrMror MVoM Y ffff −MVoM Y rrMror (2) Table 1. Structural parameters including SB2 and SL21 ordering parameters unit cell constant and the site occupation for the as-cast Mn2−xCoxVAl samples. Co content (x) Atoms X site Y site Z site SB2 SL21 alat (nm)
热处理降低Mn2-xCoxVAl Heusler合金中的取代无序
Heusler合金的X2YZ - l21型晶体结构。图3所示。铸态Mn2-xCoxVAl样品的室温x射线衍射图。数据被归一化为(220)反射的强度。粉末冶金与先进材料- RoPM&AM 2017 Materials Research Forum LLC Materials Research Proceedings 8 (2018) 211 -227 doi: http://dx.doi.org/10.21741/9781945291999-25 222铸态Mn2−xCoxVAl (x = 0,0.2, 0.6和1)合金的室温x射线衍射图如图3所示。XRD分析结果表明,铸态合金为单相结晶,属于X2YZ Heusler型结构,立方空间群Fm3 μ m(空间群no.;225),其中Mn和Co原子占据8c Wyckoff位(X),而V和Al原子分别位于4a (Y)和4b (Z)晶体位(见图2)。XRD谱图的(111)和(200)超晶格衍射线证明,Mn2-xCoxVAl合金均表现出完整Heusler合金的稳定L21结构。从(111)面反射的消光表明V原子和Al原子之间的混合。同样,如果所有Mn、V和Al原子混合,则超晶格反射(111)和(200)都将消失[1,4,8]。我们采用Takamura的模型来研究我们的Mn2−xCoxVAl (x = 0,0.2, 0.6和1)合金中的取代无序。在该模型中,定义了两种排序参数来描述原子位置之间的混合。SB2阶参数描述了Mn原子在X2YZ全Heusler合金中占据X位(8c)的概率,定义为:SB2 = MMM oM X - MMM oM X rrMror MMM oM X ffff - MMM oM X rrMror(1);二级参数SL21描述了V原子在X2YZ全Heusler合金中占据Y位的概率:SL21 = MVoM Y - MVoM Y rrMror MVoM Y ffff - MVoM Y rrMror(2)。铸态Mn2−xCoxVAl样品的结构参数包括SB2和SL21排序参数、单元常数和位点占用。Co含量(x)原子数x位Y位Z位SB2 SL21 alat (nm)
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信