{"title":"Green Synthesis of New Derivatives of Pyrrolopyrimidine by Employing Cu@KF/Clinoptilolite NPs: Study of Antioxidant Activity","authors":"","doi":"10.1080/10406638.2023.2242553","DOIUrl":null,"url":null,"abstract":"<div><p>In order to create Pyrrolo pyrimidine derivatives, multicomponent reactions involving butanoates, aldehydes, guanidine, activated acetylenic compounds, and ethyl bromopyruvate were carried out in water at room temperature with catalytic amounts of Cu@KF/CP NPs as a high-performance catalyst. Additionally, experiments involving the reducing power of ferric ions and radical trapping by DPPH were conducted to investigate the antioxidant capacity. As a result, the produced compounds exhibit excellent DPPH radical trapping and good ferric ion reduction capacity. The current method offers advantages including good reaction yield, green media, and simple product and catalyst separation.</p></div>","PeriodicalId":20303,"journal":{"name":"Polycyclic Aromatic Compounds","volume":null,"pages":null},"PeriodicalIF":2.4000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polycyclic Aromatic Compounds","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S104066382301967X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
In order to create Pyrrolo pyrimidine derivatives, multicomponent reactions involving butanoates, aldehydes, guanidine, activated acetylenic compounds, and ethyl bromopyruvate were carried out in water at room temperature with catalytic amounts of Cu@KF/CP NPs as a high-performance catalyst. Additionally, experiments involving the reducing power of ferric ions and radical trapping by DPPH were conducted to investigate the antioxidant capacity. As a result, the produced compounds exhibit excellent DPPH radical trapping and good ferric ion reduction capacity. The current method offers advantages including good reaction yield, green media, and simple product and catalyst separation.
期刊介绍:
The purpose of Polycyclic Aromatic Compounds is to provide an international and interdisciplinary forum for all aspects of research related to polycyclic aromatic compounds (PAC). Topics range from fundamental research in chemistry (including synthetic and theoretical chemistry) and physics (including astrophysics), as well as thermodynamics, spectroscopy, analytical methods, and biology to applied studies in environmental science, biochemistry, toxicology, and industry. Polycyclic Aromatic Compounds has an outstanding Editorial Board and offers a rapid and efficient peer review process, as well as a flexible open access policy.