Ionic Pt(II) Complexes Containing bis(Diphenylthiophosphinyl)methane

Synthesis and Reactivity in Inorganic and Metal-organic Chemistry Pub Date : 2004-12-01 DOI:10.1081/SIM-200030224

S. Irişli, Leman Alkan

引用次数: 3

Abstract

Abstract In this study, dipositive platinum(II) complexes of the general formula [Pt(L–L)(dppmS2)](ClO4)2, where dppmS2 = Ph2P(S)CH2P(S)Ph2 and L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), and dppp (Ph2PCH2CH2CH2PPh2), have been synthesized and characterized by 31P{1H} NMR, 13C NMR, IR spectra and elemental analyses.

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含二(二苯基硫代膦基)甲烷的离子Pt(II)配合物

摘要本文合成了一种分子式为[Pt(L-L)(dppmS2)](ClO4)2的二正铂(II)配合物，其中dppmS2 = Ph2P(S)CH2P(S)Ph2, L-L = dppm (Ph2PCH2PPh2)、dppe (Ph2PCH2CH2PPh2)和dppp (Ph2PCH2CH2PPh2)，并通过31P{1H} NMR、13C NMR、IR光谱和元素分析对其进行了表征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis and Reactivity in Inorganic and Metal-organic Chemistry

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