Chiral crystallization of anti-dodecaisopropyltricyclo-[4.2.00.0(2,5)] octasilane.

Abstract

The aim of this article is to describe the results of our investigation on the chiral crystallization of anti-tricyclic ladder polysilane, anti-dodecaisopropyltricyclo [4.2.0.0(2,5)] octasilane (1). In solid state, the silicon framework of 1 adopts twisted conformation in which the Si4 rings are puckered in the same direction. Crystallization of 1 afforded a large conglomerate crystal in high yield. X-ray crystallography revealed that the crystal consists of either right-handed (P) or left-handed (M) molecules. The ultraviolet and circular dichroism spectra of the chiral crystals of 1 reveal two absorption bands in the 400-250 nm region.