Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of LProline by Hexacyanoferrate(III) in Aqueous Alkali

The Open Catalysis Journal Pub Date : 2011-01-28 DOI:10.2174/1876214X01104010001

K. Sharanabasamma, Mahantesh A. Angadi, S. M. Tuwar

引用次数: 10

Abstract

Kinetics of ruthenium(III) catalyzed oxidation of L-proline by hexacyanoferrate(III)(HCF) in alkali was studied spectrophotometrically at 30 0 C. A reaction was found to be independent upon (L-proline). The reaction was occurred without intervening free radical. Since unit order each in (Ru(III)) and (HCF), the oxidation follows an outer-sphere mechanism. A suitable mechanism was proposed and rate law was derived as kobs = kK

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六氰高铁酸盐(III)在水溶液中钌(III)催化氧化l脯氨酸的动力学及机理

用分光光度法研究了钌(III)在30℃下催化l -脯氨酸被六氰高铁酸盐(III)(HCF)在碱中氧化的动力学，发现反应与(l -脯氨酸)无关。该反应在没有自由基干预的情况下发生。由于(Ru(III))和(HCF)均为单位序，因此氧化遵循外球机制。提出了一种合适的反应机理，并推导出速率规律为kobs = kK

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

The Open Catalysis Journal

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