Microwave-Assisted Synthesis and Characterization of Carba- and Triazolehemiporphyrazines with Camphorapyrazine Fragments

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Macroheterocycles Pub Date : 2021-01-01 DOI:10.6060/mhc210336k

A. S. Kuznetsova, M. Islyaikin, T. Torres

引用次数: 0

Abstract

A series of new hemiporphyrazines bearing camphorapyrazine fragments were synthesized using microwave assisted solvent-free protocol by interaction of m-phenylenediamine, 1(H)- or 1-dodecyl-3,5-diamino-1,2,4-triazole with racemic mixture, R-(+)- or S-(-)-camphoradicyanopyrazines. The obtained macroheterocycles were characterized by mass spectrometry, UV-Vis, IR, 1 H and 13 C NMR spectroscopy and elemental analysis data.

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Camphorapyrazine片段微波辅助合成Carba-和Triazolehemiporphyrazines及表征

以间苯二胺、1(H)-或1-十二烷基-3,5-二氨基-1,2,4-三唑与外消旋混合物R-(+)-或S-(-)-樟脑二氨基吡嗪为原料，采用微波辅助无溶剂法合成了一系列含樟脑吡嗪片段的新型半卟啉类化合物。用质谱、紫外可见光谱、红外光谱、1h和13c核磁共振光谱及元素分析数据对合成的大杂环化合物进行了表征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Macroheterocycles CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

2.30

自引率

21.40%

发文量

期刊介绍： The journal is a forum for the specialists investigating macroheterocyclic compounds. It publishes original experimental and theoretical works (full papers and short communications) and reviews on synthesis, structural characterization, physical and coordination chemistry as well as practical application of macroheterocycles.