Effect of Neodymium Dopping on Morphology, Phase Changes and Magnetic Properties of Ni0.7Zn0.3NdxFe2-xO4 Ferrite Nanoparticles Synthesized by Complexing Sol-Gel Method

A. Ghasemi, M. L. Estarki, S. Torkian, G. Gordani
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Abstract

: The purpose of this study was to evaluate phase changes and magnetic properties of neodymium doped Ni 0.7 Zn 0.3 Nd x Fe 2-x O 4 (x = 0, 0.01, 0.03, 0.05, 0.07, 0.10) nanoparticles synthesized by complexing sol-gel method. In this method, triethanolamine (TEA) acted as both a gelling agent and a chelating agent. Samples were characterized by X-ray diffraction (XRD) analysis, field emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDX). XRD patterns of all synthesized samples revealed the formation of a spinel ferrite phase. Magnetic evaluation of the specimens showed that the Nd 0.01 doped sample with a quasi-spherical morphology and particle size of about 60 nm has the highest saturation magnetization of 50 emu/g and coercive force of 103 Oe.
掺钕对溶胶-凝胶络合法制备Ni0.7Zn0.3NdxFe2-xO4铁氧体纳米颗粒形貌、相变及磁性能的影响
研究了溶胶-凝胶络合法制备的掺钕Ni 0.7 Zn 0.3 Nd fe2 -x o4 (x = 0、0.01、0.03、0.05、0.07、0.10)纳米粒子的相变和磁性能。在该方法中,三乙醇胺(TEA)同时作为胶凝剂和螯合剂。采用x射线衍射(XRD)、场发射扫描电镜(FESEM)和能量色散x射线能谱(EDX)对样品进行了表征。所有合成样品的XRD图谱均显示尖晶石铁素体相的形成。样品的磁性评价表明,Nd 0.01掺杂样品具有准球形形貌,粒径约为60 nm,饱和磁化强度最高,为50 emu/g,矫顽力为103 Oe。
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