Electrocatalytic Oxidation Performance of PbO2 Composite Electrode Doped with MXenes

IF 0.6 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Xinyu Zhang Xinyu Zhang, Jiajun Li Jiajun Li, Ming Guo Ming Guo, Kaijie Ni Kaijie Ni, Ronghui Wu and Zhiyan Hu Ronghui Wu and Zhiyan Hu
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Abstract

In this study, a two-dimensional transition metal carbon/nitride (MXenes) method was used to enhance the electrocatalytic oxidation behavior of PbO2 electrode. A novel composite electrode was prepared by doping the modified MXenes into PbO2 material. The electrochemical performance was tested by electrochemical workstation. The typical cationic red X-GRL was treated by electrochemical oxidation, and the electrochemical oxidation performance of the material electrode was investigated. The results demostrated that the dyes were removed by the oxygen evolution reaction at the electrodes doped with modified MXenes by passing current. The charge transfer resistance is 12.56. The electrodes have remained stable after 20 cycles of charging and discharging. And the removal rate of cationic red X-GRL was as high as 95.19% in 120 min. A high-efficiency composite electrode was developed in this study, which increased the electrodeand#39;s performance as well as wastewater degradation efficiency, and lay the groundwork for future research into doping MXenes to improve the performance of other materials. Hence, electrode materials doped with two-dimensional structured MXenes were candidates for the removal of contaminants, especially in the field of electrochemical catalysis
掺杂MXenes的PbO2复合电极的电催化氧化性能
在本研究中,采用二维过渡金属碳/氮化物(MXenes)方法增强PbO2电极的电催化氧化行为。将改性的MXenes掺杂到PbO2材料中制备了一种新型复合电极。采用电化学工作站对其电化学性能进行了测试。对典型的阳离子红X-GRL进行了电化学氧化处理,考察了材料电极的电化学氧化性能。结果表明,在掺杂改性MXenes的电极上,通过电流发生析氧反应去除染料。电荷转移电阻为12.56。经过20次充放电循环后,电极仍然保持稳定。在120 min内,阳离子红X-GRL的去除率高达95.19%。本研究开发了一种高效复合电极,提高了电极的性能和废水降解效率,为今后掺杂MXenes改善其他材料性能的研究奠定了基础。因此,掺杂二维结构MXenes的电极材料是去除污染物的候选材料,特别是在电化学催化领域
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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
41
审稿时长
3.4 months
期刊介绍: This journal covers different research areas in the field of Chemistry. These include; Analytical Chemistry, Applied Chemistry, Biochemistry, Environmental Chemistry, Industrial Chemistry, Inorganic Chemistry, Organic Chemistry and Physical Chemistry. The journal publishes full length articles and Reviews from researchers in academia in addition to featuring comments. Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry.
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