Comparison between Nucleophilicity and Basicity Using the Principle of “Structure Determines Properties”

大学化学 Pub Date : 2020-01-01 DOI:10.3866/pku.dxhx201912070

Xingyu Chen, Xinyu Li, Zhiqian Wang

引用次数: 0

Abstract

: This paper provides a practical explanation of the comparison between nucleophilicity and basicity of nucleophiles. The similarities are explained based on the principle of “structure determines property”, and the differences are explained by combining Hard-Soft-Acid-Base theory and the steric hindrance factor.

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用“结构决定性质”原理比较亲核性和碱性

本文对亲核试剂的亲核性和碱度的比较给出了一个实际的解释。根据“结构决定性质”的原理解释其相似性，结合硬-软酸碱理论和位阻因子解释其差异性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

大学化学

自引率

0.00%

发文量

5852

期刊介绍： University Chemistry is an educational research academic journal supervised by the Ministry of Education and co-sponsored by Peking University and the Chinese Chemical Society. It was founded in 1986 and changed to a monthly publication in January 2016. Its purpose is to promote and deepen the reform of university chemistry education and serve to improve the level of chemistry teaching in my country. The main columns are: Today's Chemistry, Teaching Research and Reform, Knowledge Introduction, Chemical Experiments, Teacher-Student Chats, Future Chemists, etc. The journal has been included in many databases such as China Journal Network Full-text Database, Wanfang Database, Taiwan Huayi Database, Chinese Science and Technology Journal Database (Full-text Edition), and American Chemical Abstracts.