Evaluation of the possibility to use organic acids solutions for production of fertilizers based on horticultural mineral wool waste

Q4 Environmental Science
K. Hoffmann, K. Chęcińska, M. Huculak-Mączka, J. Hoffmann
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Abstract

The aim of the research was evaluation of the possibility to use organic acids solutions for production of fertilizers based on mineral wool waste. This substrate thanks to inert character and good air-water relationship is commonly used in greenhouse industry. Increased production of vegetable in soilless culture due to world’s population growth. However mineral wool after full crop cycle is non-biodegradable – dangerous waste. Possibility of extraction nutrients from this kind of substrate could be solution of that important environmental problem. Before analyses mineral wool waste was grinded on 0.40 mm sieve. Then the extraction process was conducted using 2 % m/m and 10 % m/m citric acid, 2 % m/m and 10 % m/m formic acid, 0.2 % m/m and 2 % m/m acetic acid for 3 and 6 hours at temperature 25 C. Solid phase before analyses was mineralized. Iron, phosphorus was analyzed using spectrophotometer methods. Iron analysis is based on formation of a coloured ferric ion complex with 2,2’-bipyridyl. Phosphorus analysis is based on formation of molybdenum blue complex. Calcium and magnesium was examined by complexometric titration with EDTA and using Eriochrome Black T as an indicator, while calcium ions concentration was analyzed using calconcarboxylic acid as an indicator. Content of nutrients after extraction from mineral wool waste allows to conclude that obtained liquid phase can be used as a fertilizer component while solid phase can be used in mixed substrate production.
利用有机酸溶液生产以园艺矿棉废料为基础的肥料的可能性评价
该研究的目的是评估使用有机酸溶液生产基于矿棉废料的肥料的可能性。该基材具有惰性和良好的气水关系,在温室工业中得到广泛应用。由于世界人口增长,无土栽培蔬菜产量增加。然而,矿棉在整个作物周期后是不可生物降解的危险废物。从这种基质中提取营养物质的可能性可以解决这一重要的环境问题。分析前,矿棉废料在0.40 mm筛上研磨。然后用2% m/m和10% m/m的柠檬酸、2% m/m和10% m/m的甲酸、0.2% m/m和2% m/m的乙酸在温度25℃下分别提取3和6小时。用分光光度法对铁、磷进行了分析。铁分析是基于与2,2 ' -联吡啶形成有色铁离子络合物。磷的分析是基于钼蓝络合物的形成。以EDTA络合滴定法测定钙、镁,以Eriochrome Black T为指示剂,以钙羧酸为指示剂测定钙离子浓度。从矿棉废料提取后的营养成分含量可以得出结论,所得的液相可以用作肥料成分,而固相可以用于混合基质生产。
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