DETERMINAÇÃO DOS PARÂMETROS CINÉTICOS DE DEGRADAÇÃO E ESTIMATIVA DO TEMPO DE FALHA DE CONTRAMEDIDAS ELETRÔNICAS “FLARE” DO TIPO MAGNÉSIO TEFLON® VITON®

IF 0.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Carlos Rodrigues, Edemar Kirchhof, J. Rocco
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引用次数: 0

Abstract

DETERMINATION OF DEGRADATION KINETIC PARAMETERS AND FAILURE TIME ESTIMATION OF MAGNESIUM TEFLON® VITON® ELECTRONIC “FLARE” COUNTERMEASURES. Flare type countermeasures that use the composition designated as MTV (Magnesium, Teflon®, Viton®), are the most used by Air Forces around the world. In Brazil, these “flares” are used in several locations and are subjected to different handling, storage and operation conditions that can affect their performance and compromise their service life. In this work, the Monte Carlo method was applied to estimate an empirical model to predict the lifetime of these countermeasures, using as variables the temperature and the relative humidity of the place where the material is used. The results were analyzed using multiple linear regression and analysis of variance. The kinetic parameters of material thermal degradation, such as Activation Energy and Pre-exponential Factor, and the estimated failure times of these countermeasures were determined. The results pointed out to strong temperature influence on material degradation resulting in different lifetimes for each site studied.
测定镁特氟隆®VITON®型“火炬”电子对抗装置的降解动力学参数和失效时间估计
铁氟隆®viton®电子“耀斑”对策的降解动力学参数测定和失效时间估计。使用指定为MTV(镁,特氟龙®,Viton®)的成分的耀斑型对抗措施是世界各地空军使用最多的。在巴西,这些“照明弹”在多个地点使用,受到不同的处理、储存和操作条件的影响,可能会影响其性能并影响其使用寿命。在这项工作中,蒙特卡罗方法被应用于估计一个经验模型来预测这些对策的寿命,使用材料使用的地方的温度和相对湿度作为变量。采用多元线性回归和方差分析对结果进行分析。确定了材料热降解的动力学参数,如活化能和指数前因子,以及这些对策的估计失效次数。结果表明,温度对材料降解的影响较大,导致每个研究地点的材料寿命不同。
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来源期刊
Quimica Nova
Quimica Nova 化学-化学综合
CiteScore
1.60
自引率
12.50%
发文量
72
审稿时长
2-4 weeks
期刊介绍: Química Nova publishes in portuguese, spanish and english, original research articles, revisions, technical notes and articles about education in chemistry. All the manuscripts submitted to QN are evaluated by, at least, two reviewers (from Brazil and abroad) of recognized expertise in the field of chemistry involved in the manuscript. The Editorial Council can be eventually asked to review manuscripts. Editors are responsible for the final edition of QN.
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