Nicolás M. Bertero, Carlos R. Apesteguía and Alberto J. Marchi
{"title":"Synthesis of indene in the liquid phase by a one-pot process using orthogonal tandem catalysis†","authors":"Nicolás M. Bertero, Carlos R. Apesteguía and Alberto J. Marchi","doi":"10.1039/D3RE00389B","DOIUrl":null,"url":null,"abstract":"<p >The one-pot synthesis of valuable indene from 1-indanone in the liquid phase was investigated using unassisted and assisted orthogonal tandem catalysis with a mechanical mixture of Cu/SiO<small><sub>2</sub></small> and HZSM-5. An indene yield of about 80% was achieved with assisted orthogonal tandem catalysis, varying the temperature and H<small><sub>2</sub></small> pressure during the process.</p>","PeriodicalId":101,"journal":{"name":"Reaction Chemistry & Engineering","volume":" 11","pages":" 2703-2709"},"PeriodicalIF":3.4000,"publicationDate":"2023-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reaction Chemistry & Engineering","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2023/re/d3re00389b","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The one-pot synthesis of valuable indene from 1-indanone in the liquid phase was investigated using unassisted and assisted orthogonal tandem catalysis with a mechanical mixture of Cu/SiO2 and HZSM-5. An indene yield of about 80% was achieved with assisted orthogonal tandem catalysis, varying the temperature and H2 pressure during the process.
期刊介绍:
Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society.
From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.