High-Spin Iron(III) Complex with 2-(2-Imidazolyl)phenolate

IF 0.1 Q4 CRYSTALLOGRAPHY
R. Mitsuhashi, S. Hosoya, Takayoshi Suzuki, M. Mikuriya
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引用次数: 0

Abstract

were collected by filtration. The crystal data are listed in Table 1. X-ray crystallographic data were collected on a Bruker smart APEX CCD diffractometer at 90 K. The The crystal structure of tris{2-(2-imidazolyl)phenolato}iron(III), which was synthesized by a reaction of Fe(BF 4 ) 2 ·6H 2 O and 2-(2-imidazolyl)phenolate in methanol, was determined by X-ray crystallography. The compound crystallized in the trigonal space group R -3 and Z = 6 with cell parameters a = 15.830(3)Å, c = 19.973(4)Å, V = 4334.4(18)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values are 0.0385 and 0.1005, respectively, for all 2337 independent reflections. The iron atom is coordinated by three 2-(2-imdazolyl)phenolato ligands in a facial N 3 O 3 configuration, where the solvent methanol molecules are hydrogen-bonded to the phenolato-oxygen atoms.
高自旋铁(III)与2-(2-咪唑基)酚酸酯配合物
经过滤收集。晶体数据列于表1。x射线晶体学数据在90k的Bruker智能APEX CCD衍射仪上收集。用x射线晶体学方法测定了Fe(bf4) 2·6h2o与2-(2-咪唑基)苯酚在甲醇中反应合成的三{2-(2-咪唑基)苯酚}铁(III)的晶体结构。该化合物在三角形空间群R -3和Z = 6中结晶,晶胞参数a = 15.830(3)Å, c = 19.973(4)Å, V = 4334.4(18)Å 3。所有2337个独立反射的R 1 [I > 2 σ (I)]和wR 2(所有数据)值分别为0.0385和0.1005。铁原子由3个2-(2-咪唑基)苯酚配体配位,表面呈n3o - 3构型,其中溶剂甲醇分子与苯酚氧原子成氢键。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
0.60
自引率
50.00%
发文量
17
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