Crystallization of Palladium(II)-Pyridylazophenol Complex at the Liquid-Liquid Interface

IF 0.6 4区工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY

Solvent Extraction Research and Development, Japan Pub Date : 2021-01-01 DOI:10.15261/SERDJ.28.133

A. Ohashi, Takafusa Kiminarita

引用次数: 0

Abstract

The crystallization of the palladium(II) complex with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (HL) at the liquid-liquid interface was investigated in the heptane-toluene mixture/water system. Interfacial crystallization of PdLCl did not occur in the heptane/water system, whereas it occurred in the heptane-toluene mixture/water system. The crystal size distribution of PdLCl formed at the liquid-liquid interface strongly depended on the PdLCl solubility in the organic phase and the formation rate. Larger PdLCl crystals formed at the liquid-liquid interface under the higher toluene ratio, higher Pd(II) concentration and lower pH conditions.

查看原文本刊更多论文

钯(II)-吡啶偶氮酚配合物在液-液界面上的结晶

研究了钯(II)配合物与2-(5-溴-2-吡啶偶氮)-5-二乙基氨基苯酚(HL)在庚烷-甲苯混合物/水体系液-液界面处的结晶。PdLCl在庚烷/水体系中不发生界面结晶，而在庚烷-甲苯混合物/水体系中发生界面结晶。在液-液界面形成的PdLCl晶体尺寸分布与PdLCl在有机相中的溶解度和形成速率密切相关。在较高的甲苯比、较高的Pd(II)浓度和较低的pH条件下，液液界面形成较大的PdLCl晶体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Solvent Extraction Research and Development, Japan 工程技术-工程：化工

CiteScore

1.30

自引率

14.30%

发文量

审稿时长

1 months

期刊介绍： Solvent Extraction Research and Development, Japan (Solvent Extr. Res. Dev., Jpn.) is a periodical issued from Japan Association of Solvent Extraction (JASE) containing papers dealing with all aspects of solvent extraction and their related methods, underlying principles, and materials. Original articles, notes, technical reports, and critical reviews will be considered for publication. Original articles must be of reasonably broad scope and significance to the solvent extraction. Notes will originally describe novel work of a limited nature or especially significant work in progress. Authors can contribute some information of novel techniques, equipment or apparatus, reagents and diluents for solvent extraction as technical reports. Critical reviews will be received from the authors to whom the editorial committee asked to contribute.