Flexible ein-und zweikernige Aralkyl-und Aralkoxyquecksilberverbindungen als Modelle zum Nachweis von Hg(II)-Hg(II)-W echselwirkungen / Flexible Mono-and Dinuclear Aralkyl and Aralkoxy Mercury Compounds for Detection of Hg (II)-Hg (II) Interactions

IF 0.8 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences Pub Date : 1992-01-01 DOI:10.1515/znb-1992-0306

Hans-Jürgen Öller, P. Kiprof, H. Schmidbaur

引用次数: 0

Abstract

The aralkyl and aralkoxy mercury(II) compounds 1-(chloromercury(II)methyl)naphthalene (1), bis[1-naphthylmethyl]mercury(II) (2), 1-naphthyl(1-naphthylmethyl)mercury(II) (3), 1,8-bis[chloromercury(II)methyl]naphthalene (4), methylmercury(II)-benzylate (5), methylmercury( II)-1-naphthylmethylate (6) and bis[methylmercury(II)]μ-1,8-naphthalenediyl-bismethylate (7) have been prepared and characterized by means of NMRspectroscopy, mass spectrometry and elemental analysis. The molecular structure of compound 2 has been determined by single X-ray crystallography. The unit cell of 2 contains two crystallographically independent molecules, one of which is disordered. The interatomic distances and angles meet the expectations with Hg ⋯ Hg separations larger than 5.60 Å, indicating the absence of metal metal interactions.

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Hg(II)-Hg(II)-W echselwirkungen /单核和双核芳烷基和芳烷氧基汞化合物检测Hg(II)-Hg(II)相互作用

制备了芳烷基和芳烷氧基汞(II)化合物1-(氯汞(II)甲基)萘(1)、二[1-萘甲基]汞(II)(2)、1-萘甲基(1-萘甲基)汞(II)(3)、1,8-二[氯汞(II)甲基]萘(4)、甲基汞(II)-苄基酸盐(5)、甲基汞(II)- 1-萘甲基化盐(6)和二[甲基汞(II)]μ-1,8-萘二基双甲基化盐(7)，并用核磁共振光谱、质谱和元素分析对其进行了表征。化合物2的分子结构已用单x射线晶体学测定。2的单晶胞包含两个晶体学上独立的分子，其中一个是无序的。原子间距离和角度符合预期，汞⋯⋯汞分离大于5.60 Å，表明不存在金属间相互作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences 化学-无机化学与核化学

CiteScore

1.80

自引率

12.50%

发文量

期刊介绍： Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur. Topics Solid state chemistry Coordination chemistry Main group element chemistry Organic chemistry Natural product chemistry.