Deca(4-methylbenzyl)ferrocen und -stannocen

IF 0.8 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences Pub Date : 2005-01-01 DOI:10.14279/depositonce-7498

H. Schumann, Klaudia Sühring, Roman Weimann, Markus Hummert

引用次数: 1

Abstract

Cyclopentadiene reacts with five equivalents of 4-methylbenzylalcohol (1:5,6 mole ratio) and sodium yielding penta(4-methylbenzyl)cyclopenta-2,4-diene (1), which upon treatment with butyl lithium affords the lithium salt [(4-MeC 6 H 4 CH 2 ) 5 C 5 ]Li (2). The reactions of 2 with FeCl 2 and SnCl 2 result in the formation of deca(4-methylbenzyl)ferrocene (3) and deca(4-methylbenzyl)stannocene (4), respectively. The 1 H and 1 3 C NMR, IR and mass spectra of the new compounds as well as the single crystal X-ray structure analysis of 1 are reported and discussed.

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二

环戊二烯与5个等量的4-甲基苄基醇(1:5,6摩尔比)和钠反应生成五(4-甲基苄基)环戊-2,4-二烯(1)，经丁基锂处理后得到锂盐[(4- mec 6 H 4 CH 2) 5 C 5]Li(2)。2与FeCl 2和SnCl 2反应分别生成十(4-甲基苄基)二茂铁(3)和十(4-甲基苄基)二茂铁(4)。报道并讨论了新化合物的1h和13c NMR、IR和质谱，以及1的单晶x射线结构分析。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences 化学-无机化学与核化学

CiteScore

1.80

自引率

12.50%

发文量

期刊介绍： Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur. Topics Solid state chemistry Coordination chemistry Main group element chemistry Organic chemistry Natural product chemistry.