Versatile nonlinear-optical materials based on mesomorphic metal alkanoates: design, properties, and applications

IF 4.8 3区材料科学 Q2 CHEMISTRY, PHYSICAL

Liquid Crystals Reviews Pub Date : 2015-01-02 DOI:10.1080/21680396.2015.1030461

G. Klimusheva, T. Mirnaya, Y. Garbovskiy

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引用次数: 32

Abstract

Metal alkanoates combine simple chemical structures and a versatility of condensed states of matter they exhibit. Solid crystals, plastic crystals, lyotropic and thermotropic ionic liquid crystals, liquids, mesomorphic glasses, and Langmuir–Blodgett films are just a few examples. Liquid crystal phases of metal alkanoates are the most intriguing because they represent a non-conventional class of materials known as ionic metallomesogens. Structural, thermal, and transport properties of mesomorphic metal alkanoates are well documented and reviewed. On the contrary, the optical and nonlinear-optical properties of these materials are very poorly understood. The situation has changed rapidly during the last decade. Advances in the design of mesomorphic glasses stable at room temperatures have launched a new era of research in the field of photonic and optoelectronic materials based on mesomorphic metal alkanoates. This manuscript reviews recent developments in the field of optical and nonlinear-optical materials based on mesomorphic metal alkanoates.

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基于介形金属烷酸酯的多功能非线性光学材料:设计、性能和应用

金属烷酸盐结合了简单的化学结构和它们所表现出的多种凝聚态。固体晶体、塑料晶体、溶致性和热致性离子液晶、液体、中晶玻璃和Langmuir-Blodgett薄膜就是其中的几个例子。金属烷酸酯的液晶相是最吸引人的，因为它们代表了一种被称为离子金属生成的非常规材料。介形金属烷酸酯的结构、热学和输运性质得到了很好的记录和评述。相反，人们对这些材料的光学性质和非线性光学性质了解甚少。在过去十年中，情况发生了迅速变化。室温稳定的亚晶玻璃的设计进展开启了基于亚晶金属烷酸盐的光子和光电子材料研究的新时代。本文综述了基于介形金属烷酸酯的光学和非线性光学材料领域的最新进展。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Liquid Crystals Reviews CHEMISTRY, PHYSICALCRYSTALLOGRAPHY&n-CRYSTALLOGRAPHY

CiteScore

7.60

自引率

5.90%

发文量

期刊介绍： Liquid Crystals Reviews publishes review articles on all aspects of liquid crystal fundamentals and applied science, including experimental and theoretical studies of physical and chemical properties, molecular design and synthesis and engineering of liquid crystal devices. The Journal fosters cross-disciplinary exchange of ideas, encouraging authors to present material at a level accessible to specialists from other fields of science and engineering. Liquid Crystals Reviews provides the scientific community, in both academia and industry, with a publication of standing, guaranteed by the Editors and by the International Editorial Board who are active scientists in the worldwide liquid crystal community.