Recent advances in chemistry of high-spin nitrenes

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Reviews Pub Date : 2021-01-01 DOI:10.1070/RCR4965

S. Chapyshev, D. Korchagin, E. Y. Misochko

引用次数: 0

Abstract

Experimental and theoretical studies on aromatic nitrenes bearing from three to six unpaired electrons and having quartet, quintet, sextet or septet ground spin states, published in the last 15 years are analyzed. A comparative analysis of the magnetic properties of high-spin nitrenes and all other known high-spin organic molecules is performed. Promising areas of practical application of high-spin nitrenes as molecular magnets and as qubits and qudits for quantum computations are discussed. The bibliography includes 214 references.

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高自旋亚硝基烯的化学研究进展

本文分析了近15年来关于含有3 ~ 6个未配对电子并具有四重奏、五重奏、六重奏或七重奏基态的芳香亚硝基烯的实验和理论研究。比较分析了高自旋亚硝基烯和所有其他已知的高自旋有机分子的磁性能。讨论了高自旋亚硝基烯在分子磁体、量子比特和量子计算中的应用前景。参考书目包括214篇参考文献。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Chemical Reviews 化学-化学综合

CiteScore

13.00

自引率

5.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Russian Chemical Reviews serves as a complete translation of the esteemed monthly review journal Uspekhi Khimii, which has been a prominent figure in Russian scientific journals since its establishment in 1932. It offers comprehensive access to the advancements made by chemists from Russia and other former Soviet Union countries. Established in 1932, Russian Chemical Reviews is committed to publishing timely and significant review articles encompassing various facets of modern chemistry, including chemical physics, physical chemistry, computational and theoretical chemistry, catalysis, coordination chemistry, analytical chemistry, organic, organometallic, and organoelement chemistry, chemistry of macromolecules, applied chemistry, biochemistry, bio-organic chemistry, biomolecular chemistry, medicinal chemistry, materials chemistry, nanochemistry, nanostructures, and environmental chemistry.