{"title":"Synthesis of nanoporous copper terephthalate [MIL-53(Cu)] as a novel methane-storage adsorbent","authors":"Mansoor Anbia, Sara Sheykhi","doi":"10.1016/S1003-9953(11)60419-2","DOIUrl":null,"url":null,"abstract":"<div><p>Copper (II) dicarboxylate, MIL-53, metal-organic framework synthesized hydrothermally has been used for the first time as an adsorbent for methane gas adsorption. Methane adsorption capacity of MIL-53(Cu) was increased to about 8.52 mmol·g<sup>−1</sup> at 298 K and 35 bar for methane storage. The adsorbent was characterized by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) method, Fourier transform infrared (FT-IR), thermo gravimetric analysis (TGA) and scanning electron microscopy (SEM). The adsorption property of CH<sub>4</sub>, on MIL-53(Cu) was investigated by volumetric measurement. The enhancement of CH<sub>4</sub> adsorption capacity of MIL-53(Cu) is attributed to the increase of micropore volume of MIL-53(Cu).</p></div>","PeriodicalId":56116,"journal":{"name":"Journal of Natural Gas Chemistry","volume":"21 6","pages":"Pages 680-684"},"PeriodicalIF":0.0000,"publicationDate":"2012-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1003-9953(11)60419-2","citationCount":"20","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Natural Gas Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1003995311604192","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 20
Abstract
Copper (II) dicarboxylate, MIL-53, metal-organic framework synthesized hydrothermally has been used for the first time as an adsorbent for methane gas adsorption. Methane adsorption capacity of MIL-53(Cu) was increased to about 8.52 mmol·g−1 at 298 K and 35 bar for methane storage. The adsorbent was characterized by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) method, Fourier transform infrared (FT-IR), thermo gravimetric analysis (TGA) and scanning electron microscopy (SEM). The adsorption property of CH4, on MIL-53(Cu) was investigated by volumetric measurement. The enhancement of CH4 adsorption capacity of MIL-53(Cu) is attributed to the increase of micropore volume of MIL-53(Cu).
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
