Effect of preparation method on halloysite supported cobalt catalysts for Fischer-Tropsch synthesis

Sufang Chen , Jinlin Li , Yuhua Zhang , Daohong Zhang , Junjiang Zhu
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引用次数: 24

Abstract

Novel cobalt Fischer-Tropsch synthesis (FTS) catalysts were prepared from natural halloysite nanotubes (HNT) by double-solvent and wet-impregnation methods, and characterized by TEM, XRD, TPR and N2 adsorption-desorption. Comparing with the catalyst prepared by wet-impregnation method, the catalyst prepared by double-solvent method reduces Co3O4 particle migration and agglomeration due to size-induced effect, thus showing higher catalytic activity for Fischer-Tropsch synthesis.

制备方法对高岭土载钴费托合成催化剂的影响
以天然高岭土纳米管(HNT)为原料,采用双溶剂和湿浸渍法制备了新型钴费托合成(FTS)催化剂,并采用TEM、XRD、TPR和N2吸附-脱附等手段对催化剂进行了表征。与湿浸染法制备的催化剂相比,双溶剂法制备的催化剂由于尺寸诱导效应减少了Co3O4颗粒的迁移和团聚,对费托合成表现出更高的催化活性。
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来源期刊
Journal of Natural Gas Chemistry
Journal of Natural Gas Chemistry 化学-工程:化工
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