Cis- and Trans-Coordination Assembly of Nitrogen Heterocycle with Copper(II) and Silver(I)

IF 3.1 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Research in Chinese Universities Pub Date : 2008-11-01 DOI:10.1016/S1005-9040(09)60001-5

Di TAN , Gui-ping TAN , Xiao-chun HUANG , Shan-ling TONG , Ke-er YANG , Yan YAN

引用次数: 1

Abstract

After the preparation of 1,4-bis(4,5-dihydro-1H-imidazol-2-yl)benzene(bdib), a nitrogen heterocycle with potential coordination manners of both cis- and trans-configuration forms, three complexes, including cis-[Cu₂(bdib)₂(μ-OCH₃)₂]Cl₂·2MeOH(1), trans-[Cu(bdib)(AcO)₂]_n(2), and cis-[Ag₂(bdib)₂](NO₃)₂-2H₂O(3), were successfully self-assembled. Complexes 1 and 2 crystallized in the monoclinic system with P2₁/n space group and complex 3 in the triclinic system with P1 space group.

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氮杂环与铜(II)和银(I)的顺式和反式配位组装

在制备了具有顺式和反式两种配位方式的氮杂环1,4-双(4,5-二氢- 1h -咪唑-2-基)苯(bdib)后，成功地自组装了顺式-[Cu2(bdib)2(μ-OCH3)2]Cl2·2MeOH(1)、反式-[Cu(bdib)(AcO)2]n(2)和顺式-[Ag2(bdib)2](NO3)2- 2h2o(3)三个配合物。配合物1和2在具有P21/n空间群的单斜体系中结晶，配合物3在具有P1空间群的三斜体系中结晶。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Research in Chinese Universities 化学-化学综合

CiteScore

5.30

自引率

6.50%

发文量

152

审稿时长

3.0 months

期刊介绍： The journal publishes research articles, letters/communications and reviews written by faculty members, researchers and postgraduates in universities, colleges and research institutes all over China and overseas. It reports the latest and most creative results of important fundamental research in all aspects of chemistry and of developments with significant consequences across subdisciplines. Main research areas include (but are not limited to): Organic chemistry (synthesis, characterization, and application); Inorganic chemistry (bio-inorganic chemistry, inorganic material chemistry); Analytical chemistry (especially chemometrics and the application of instrumental analysis and spectroscopy); Physical chemistry (mechanisms, catalysis, thermodynamics and dynamics); Polymer chemistry and polymer physics (mechanisms, material, catalysis, thermodynamics and dynamics); Quantum chemistry (quantum mechanical theory, quantum partition function, quantum statistical mechanics); Biochemistry; Biochemical engineering; Medicinal chemistry; Nanoscience (nanochemistry, nanomaterials).