{"title":"A study of the electro reduction of metaphosphate in molten LiCl-KCl eutectic","authors":"H.A. Laitinen, K.R. Lucas","doi":"10.1016/0022-0728(66)80135-3","DOIUrl":null,"url":null,"abstract":"<div><p>The reduction of trimetaphosphate in LiCl-KCl eutectic has been studied over the temperature range 450–700° using voltammetry, chronopotentiometry, and coulometry. The reduction process was observed to be very complex even at the highest temperatures because of prior chemical reactions. A reduction scheme is proposed that is consistent with experimental observations.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 5","pages":"Pages 553-563"},"PeriodicalIF":0.0000,"publicationDate":"1966-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80135-3","citationCount":"11","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry (1959)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022072866801353","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 11
Abstract
The reduction of trimetaphosphate in LiCl-KCl eutectic has been studied over the temperature range 450–700° using voltammetry, chronopotentiometry, and coulometry. The reduction process was observed to be very complex even at the highest temperatures because of prior chemical reactions. A reduction scheme is proposed that is consistent with experimental observations.