{"title":"Etude thermodynamique de la dissociation du γ-glutamate d'ethyle","authors":"J. Llopis, A. Vallin","doi":"10.1016/0022-0728(66)80122-5","DOIUrl":null,"url":null,"abstract":"<div><p>The ionization constants of γ-ethyl glutamate have been determined, from 5–50° from e.m.f. measurements of cells without liquid junctions. The equations for ionization constants as a function of temperature are as follows : <figure><img></figure></p><p>Values for the derived thermodynamic quantities have been calculated. The results were interpreted in relation to those known for glutamic acid and α-amino-esters.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 5","pages":"Pages 422-435"},"PeriodicalIF":0.0000,"publicationDate":"1966-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80122-5","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry (1959)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022072866801225","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The ionization constants of γ-ethyl glutamate have been determined, from 5–50° from e.m.f. measurements of cells without liquid junctions. The equations for ionization constants as a function of temperature are as follows :
Values for the derived thermodynamic quantities have been calculated. The results were interpreted in relation to those known for glutamic acid and α-amino-esters.