Coulometric titration of oxidizing agents with electrogenerated molybdenum(V)

Abstract

The coulometric titration of several oxidizing agents with Mo(V) has been investigated. Permanganate, persulfate, Ce(IV), vanadate, iodate, and ferricyanide reacted stoichiometrically. Bromine, bromate, iodine, and chlorate reacted too slowly to be titrated directly. Fe(III), tungstate, uranyl, and Ti(IV) did not titrate.