Deposition of the most acidifying components in The Netherlands during the period 1980–1986

Jan-Willem Erisman, Frank A.A.M. De Leeuw, Roel M. Van Aalst
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引用次数: 50

Abstract

Detailed maps of the deposition of acidifying components in The Netherlands are presented. The deposition was estimated from measurements of concentrations in the atmosphere and precipitation. Lack of information on the concentration of ammonia and ammonium in air made it impossible to estimate dry deposition. Therefore, these were estimated by model calculations. The nationwide averaged deposition of total (potential) acid in 1980 was ca. 5800 mol H+ ha−1 a−1. The most important acidifying components are sulphur oxides, nitrogen oxides and ammonia and their reaction products. Sulphur compounds (SOx) contributed about 49%, reduced nitrogen species (NHx) 23% and oxidized nitrogen species (NOty) 28% to the total deposition. Wet deposition contributes 30% to the total deposition. The spatial distribution of the total deposition shows a gradient over The Netherlands with highest values in the south and lowest in the north.

In 1986 the total deposition was estimated to be ca. 4900 mol H+ ha−1 a−1 (40% SOx, 32% NOy and 28% NHx. The decrease is mainly the result of the lower SOx deposition. The relative contribution of inland emissions to the deposition in The Netherlands is about 41%. About 30% of the NH, deposition is due to foreign sources; for SOx this is about 80% and for NOy 65%. About 80% of Dutch emissions is deposited outside The Netherlands. The net export of SOx decreased between 1980 and 1985 from 150 kt a−1 to 35 kt a−1, while the net export of NOy (ca. 280 kt a−1) and NH, (ca. 155 kt a−1) has remained constant over the period 1980–1986.

1980-1986年期间荷兰最酸化成分的沉积
提出了荷兰酸化成分沉积的详细地图。沉积量是通过测量大气和降水中的浓度来估计的。由于缺乏关于空气中氨和铵浓度的资料,因此无法估计干沉降。因此,这些都是通过模型计算来估计的。1980年全国总(势)酸平均沉积量约为5800 mol H+ ha−1 a−1。最重要的酸化成分是硫氧化物、氮氧化物和氨及其反应产物。硫化合物(SOx)占总沉积量的49%,还原态氮(NHx)占23%,氧化态氮(NOty)占28%。湿沉积占总沉积量的30%。总沉积的空间分布在荷兰呈梯度分布,南部最高,北部最低。1986年估计总沉积量约为4900 mol H+ ha−1 a−1 (40% SOx, 32% NOy和28% NHx)。减少的主要原因是硫氧化物沉积减少。内陆排放对荷兰沉积的相对贡献约为41%。约30%的NH沉积是由于外来来源;对于SOx,这一比例约为80%,对于NOy,这一比例为65%。荷兰大约80%的排放都在荷兰境外。1980年至1985年间,硫氧化物的净出口从150 kt a−1减少到35 kt a−1,而硝态氮的净出口(约280 kt a−1)和NH的净出口(约155 kt a−1)在1980年至1986年期间保持不变。
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