Estimating the creep behavior of glass-fiber-reinforced polyamide considering the effects of crystallinity and fiber volume fraction

IF 4.03
Takenobu Sakai, Yuto Hirai, Satoshi Somiya
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引用次数: 11

Abstract

The time-temperature superposition principle (TTSP) is often used to estimate the viscoelastic behavior of polymers. It can also be used to evaluate the influence of a given variable, or set of variables, on viscoelastic properties. In this research, the effects of time, temperature, fiber volume fraction and the relative crystallinity of polyamide (PA) and glass fiber-reinforced polyamide (GFRPA) were investigated using the time-temperature superposition principle to estimate viscoelastic behavior under each set of conditions.

The crystallinities of PA and GFRPA, which ranged from 33 to 45%, were controlled by adjusting the duration of crystallization as 250?°C. Creep tests were carried out with these materials, and creep compliance curves of each condition were obtained.

Using these creep compliance curves, the master curves for temperature, and the grand master curves for crystallinity and for fiber volume fraction were generated to show the relationships between fiber volume fraction, crystallinity, and viscoelastic parameters. Furthermore, the great-grand master curve for crystallinity and fiber volume fraction was generated to predict creep behavior in an arbitrarily condition. The predicted data were in good agreement with experimental results.

A method for estimating creep deformation taking into account the effects of influencing variables was developed. The time-temperature superposition principle (TTSP) was applied to the effects of the fiber volume fraction and crystallinity. Grand master curves for crystallinity and fiber volume fraction were obtained by shifting the corresponding master curves. This study demonstrates that the creep behaviors of fiber-reinforced plastics can be estimated using these shift factors and a great-grand master curve. This method yielded estimates of creep deformation that fitted well with experimental results. Based on our findings, it should be possible to control creep deformation in plastics or fiber-reinforced resins by controlling the fiber volume fraction and the crystallinity of the matrix material.

Abstract Image

考虑结晶度和纤维体积分数影响的玻璃纤维增强聚酰胺蠕变性能评价
时间-温度叠加原理(TTSP)常用于估计聚合物的粘弹性行为。它还可用于评估给定变量或一组变量对粘弹性特性的影响。采用时间-温度叠加原理,研究了时间、温度、纤维体积分数和相对结晶度对聚酰胺(PA)和玻璃纤维增强聚酰胺(GFRPA)粘弹性性能的影响。通过调节结晶时间为250°C,可以控制PA和GFRPA的结晶度,其结晶度在33 ~ 45%之间。对这些材料进行了蠕变试验,得到了各工况下的蠕变柔度曲线。利用这些蠕变柔度曲线,生成了温度的主曲线、结晶度和纤维体积分数的主曲线,以表示纤维体积分数、结晶度和粘弹性参数之间的关系。此外,还生成了结晶度和纤维体积分数的大大师曲线,用于预测任意条件下的蠕变行为。预测数据与实验结果吻合较好。提出了一种考虑影响变量影响的蠕变变形估计方法。利用时间-温度叠加原理(TTSP)研究了纤维体积分数和结晶度的影响。通过移动主曲线得到了结晶度和纤维体积分数的主曲线。该研究表明,纤维增强塑料的蠕变行为可以用这些位移因子和大大师曲线来估计。该方法估算的蠕变变形与实验结果吻合较好。根据我们的发现,应该可以通过控制纤维体积分数和基体材料的结晶度来控制塑料或纤维增强树脂的蠕变。
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