Effect of marine incursion on the formation of lacustrine source rocks: A case study of mudstones from the third member of the Shahejie Formation in the southwestern Bozhong Sag, Bohai Bay Basin, China

Qian Huang , Yaohui Xu , Feilong Wang , Haifeng Yang , Ning Wang , Jiaohao He
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Abstract

Bozhong Sag, the largest hydrocarbon generation sag in the Bohai Bay Basin, is characterized by presence of the third member of the Shahejie Formation (E2s3), which serves as a significant source rock. While previous studies have provided insights into the source material, sedimentary environment, and thermal maturity of the E2s3 source rocks, further investigation is required to deepen our understanding of sedimentary events and biological sources. In this research, nine mudstone core samples from the southwestern Bozhong Sag were thoroughly analyzed using organic-inorganic geochemistry and organic petrology. The results reveal the following key findings: (1) The middle and lower sections of the third member of the Shahejie Formation are characterized by high-quality source rocks, with the lower section exhibiting superior quality. The increase in water salinity during warm and humid climates, and the detection of 24-n-propylcholestane compounds reflected the occurrence of transgression events in the E2s3. These transgressions gradually increased from the lower sections to the middle sections of the E2s3. (2) The studied samples exhibit abundant presence of 4α-methyl-24-ethylcholestanes, 24-n-propylcholestanes, 2α-methylhopanes, oleananeabundant algainite, and a small amount of vitrinite. This diversity of hydrocarbon-forming organisms in the E2s3 source rocks is evident. (3) The moderate marine incursion in the lower part of the E2s3 results in nutrient elements that promote the flourishing of bacteria and algae, providing an abundant material basis for the formation of high-quality source rocks. However, the large-scale marine incursion in the middle of the E2s3 weakens water eutrophication, resulting in a decrease in the quality of source rocks compared to the lower part of the E2s3.

海洋入侵对湖相烃源岩形成的影响——以渤海湾盆地博中凹陷西南部沙三段泥岩为例
渤中凹陷是渤海湾盆地最大的生烃凹陷,其特征是沙三段(E2s3)的存在,是重要的烃源岩。虽然之前的研究已经深入了解了E2s3烃源岩的来源物质、沉积环境和热成熟度,但还需要进一步的研究来加深我们对沉积事件和生物来源的理解。本研究采用有机-无机地球化学和有机岩石学方法,对渤中凹陷西南部9个泥岩岩心样品进行了深入分析。研究结果表明:(1)沙三段中下段烃源岩质量较好,下段烃源质较好。温暖潮湿气候期间海水盐度的增加,以及24-正丙基胆甾烷化合物的检测,反映了E2s3海侵事件的发生。这些海侵从E2s3的下部向中部逐渐增加。(2) 所研究的样品显示出大量的4α-甲基-24-乙基胆汁烷、24-正丙基胆汁烷、2α-甲基Hopanes、富含油酸的Alganite和少量镜质组。E2s3烃源岩中成烃生物的多样性是显而易见的。(3) E2s3下部的适度海洋入侵导致营养元素促进细菌和藻类的繁殖,为形成优质烃源岩提供了丰富的物质基础。然而,与E2s3下部相比,E2s3中部的大规模海洋入侵削弱了水体富营养化,导致源岩质量下降。
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