Tailor-made microstructures lead to high-performance robust PEO membrane for CO2 capture via green fabrication technique

IF 10.7 1区 工程技术 Q1 CHEMISTRY, PHYSICAL
Wei-Shi Sun, Ming-Jie Yin, Wen-Hai Zhang, Shuo Li, Naixin Wang, Quan-Fu An
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引用次数: 6

Abstract

Emerging excessive greenhouse gas emissions pose great threats to the ecosystem, which thus requires efficient CO2 capture to mitigate the disastrous issue. In this report, large molecular size bisphenol A ethoxylate diacrylate (BPA) was employed to crosslink poly (ethylene glycol) methyl ether acrylate (PEGMEA) via the green and rapid UV polymerization strategy. The microstructure of such-prepared membrane could be conveniently tailored by tuning the ratio of the two prepolymers, aiming at obtaining the optimized microstructures with suitable mesh size and PEO sol content, which was approved by a novel low-field nuclear magnetic resonance technique. The optimum membrane overcomes the trade-off challenge: dense microstructures lower the gas permeability while loose microstructures lower high-pressure-resistance capacity, realizing a high CO2 permeability of 1711 Barrer and 100-h long-term running stability under 15 atm. The proposed membrane fabrication approach, hence, opens a novel gate for developing high-performance robust membranes for CO2 capture.

Abstract Image

量身定制的微观结构通过绿色制造技术生产出用于CO2捕获的高性能坚固PEO膜
新出现的过量温室气体排放对生态系统构成了巨大威胁,因此需要有效捕获二氧化碳来缓解这一灾难性问题。本文采用大分子量双酚A乙氧基化二丙烯酸酯(BPA),采用绿色快速紫外聚合策略交联聚乙二醇甲基醚丙烯酸酯(PEGMEA)。通过调节两种预聚物的比例,可以方便地调整这种膜的微观结构,旨在获得具有合适网孔尺寸和PEO溶胶含量的优化微观结构,这已被一种新的低场核磁共振技术所证实。最佳膜克服了权衡挑战:致密的微观结构降低了气体渗透率,而疏松的微观结构则降低了高压耐受能力,实现了1711 Barrer的高CO2渗透率和在15个大气压下100小时的长期运行稳定性。因此,所提出的膜制造方法为开发用于CO2捕获的高性能坚固膜打开了一扇新的大门。
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来源期刊
Green Energy & Environment
Green Energy & Environment Energy-Renewable Energy, Sustainability and the Environment
CiteScore
16.80
自引率
3.80%
发文量
332
审稿时长
12 days
期刊介绍: Green Energy & Environment (GEE) is an internationally recognized journal that undergoes a rigorous peer-review process. It focuses on interdisciplinary research related to green energy and the environment, covering a wide range of topics including biofuel and bioenergy, energy storage and networks, catalysis for sustainable processes, and materials for energy and the environment. GEE has a broad scope and encourages the submission of original and innovative research in both fundamental and engineering fields. Additionally, GEE serves as a platform for discussions, summaries, reviews, and previews of the impact of green energy on the eco-environment.
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