Efficient synthesis, characterization and electrochemical properties of bis(ferrocenyl) ethers

S. Dharani , Vincent M. Lynch , R. Prabhakaran
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引用次数: 0

Abstract

Three different symmetrical ethers derived from formyl ferrocene, acetyl ferrocene and benzoyl ferrocene have been characterized via FT-IR, UV-Visible and 1H NMR spectroscopic techniques. Further, the true nature of bis[phenyl(ferrocenyl)methyl]ether was confirmed by single crystal X-ray diffraction analysis. The redox behavior of ferrocenyl ethers has been studied using cyclic voltammetry. The present method yields the corresponding bisferrocenyl ether with almost 100 % conversion.

二茂铁醚的高效合成、表征及电化学性能
用红外光谱、紫外-可见光谱和核磁共振氢谱对甲酰基二茂铁、乙酰基二茂铁和苯甲酰二茂铁衍生的三种不同的对称醚进行了表征。此外,通过单晶X射线衍射分析证实了双[苯基(二茂铁基)甲基]醚的真实性质。用循环伏安法研究了二茂铁醚的氧化还原行为。本方法以几乎100%的转化率产生相应的双二茂铁醚。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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