{"title":"Efficient synthesis, characterization and electrochemical properties of bis(ferrocenyl) ethers","authors":"S. Dharani , Vincent M. Lynch , R. Prabhakaran","doi":"10.1016/j.cinorg.2023.100018","DOIUrl":null,"url":null,"abstract":"<div><p>Three different symmetrical ethers derived from formyl ferrocene, acetyl ferrocene and benzoyl ferrocene have been characterized <em>via</em> FT-IR, UV-Visible and <sup>1</sup>H NMR spectroscopic techniques. Further, the true nature of bis[phenyl(ferrocenyl)methyl]ether was confirmed by single crystal X-ray diffraction analysis. The redox behavior of ferrocenyl ethers has been studied using cyclic voltammetry. The present method yields the corresponding bisferrocenyl ether with almost 100 % conversion.</p></div>","PeriodicalId":100233,"journal":{"name":"Chemistry of Inorganic Materials","volume":"1 ","pages":"Article 100018"},"PeriodicalIF":0.0000,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Inorganic Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949746923000186","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Three different symmetrical ethers derived from formyl ferrocene, acetyl ferrocene and benzoyl ferrocene have been characterized via FT-IR, UV-Visible and 1H NMR spectroscopic techniques. Further, the true nature of bis[phenyl(ferrocenyl)methyl]ether was confirmed by single crystal X-ray diffraction analysis. The redox behavior of ferrocenyl ethers has been studied using cyclic voltammetry. The present method yields the corresponding bisferrocenyl ether with almost 100 % conversion.