The importance of elemental lead to perovskites photovoltaics

Zhiguo Zhang , Yuping Liu , Qiang Sun , Huaxia Ban , Zhirong Liu , Huaixuan Yu , Xiongjie Li , Letian Dai , Wanpeng Yang , Yan Shen , Mingkui Wang
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Abstract

Perovskite photovoltaic has been attracting intense attention as an emerging technology due to its figure of merits including high power conversion efficiency, low-cost fabrication, and others. A successful commercialization of this type of technology has been significantly retarded by issues of elemental toxicity and device stability which are related to the key component of lead (Pb) in most efficient halide perovskites. Here, we first elucidated the origin of the superior optoelectronic properties of lead halide perovskites and their impact on photovoltaic device performance. We then discussed the promising approaches to solve the toxicity issue of lead hybrid perovskites. We further outlooked the effective solutions for lead hybrid perovskites for solar cell application. This review may provide a guidance for researchers interested in facilitating perovskite solar cells from exploitation to application.

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元素铅对钙钛矿光伏的重要性
钙钛矿光伏作为一种新兴技术,由于其功率转换效率高、制造成本低等优点而备受关注。这类技术的成功商业化因元素毒性和器件稳定性问题而受到严重阻碍,这些问题与最有效的卤化物钙钛矿中的铅(Pb)的关键成分有关。在这里,我们首先阐明了卤化铅钙钛矿优异光电性能的起源及其对光伏器件性能的影响。然后,我们讨论了解决铅杂化钙钛矿毒性问题的有前景的方法。我们进一步展望了铅杂化钙钛矿在太阳能电池应用中的有效解决方案。这篇综述可能为有兴趣促进钙钛矿太阳能电池从开发到应用的研究人员提供指导。
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