{"title":"Cold Atmospheric Pressure Plasma Technology for Modifying Polymers to Enhance Adhesion: A Critical Review","authors":"H. Baniya, R. P. Guragain, D. Subedi","doi":"10.1002/9781119846703.CH19","DOIUrl":null,"url":null,"abstract":"This review summarizes the results of cold atmospheric pressure plasma technology application in polymers surface treatment. Attention is given to results of changes in the hydrophilic property of polymer surfaces by incorporation of polar functional groups when exposed to atmospheric\n pressure plasma, depending on the time of treatment, applied voltage, gas flow rate, and distance from the surface. We have successfully developed a plasma device that is able to generate cold atmospheric pressure argon plasma of low temperature (20 – 26) ° C downstream using a high-voltage\n power source which can be widely used in materials processing. Therefore, a cost-effective system of generating a plasma jet at atmospheric pressure with potential applications has been developed. Cold atmospheric pressure plasma jet (CAPPJ) has shown a lot of applications in recent years\n such as in materials processing, surface modification, and biomedical materials processing. CAPPJ has been generated by a high voltage (0-20 kV) and high frequency (20-30 kHz) power supply. The discharge has been characterized by optical and electrical methods. In order to characterize\n cold atmospheric pressure argon plasma jet, its electron density, electron temperature, rotational temperature, and vibration temperature have been determined using the power balance method, intensity ratio method, Stark broadening method, and Boltzmann plot method, respectively. The improvement\n in hydrophilicity of the cold plasma-treated polymer samples was characterized by contact angle measurements, surface free energy analysis, Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). Contact angle analysis showed that the discharge was effective\n in improving the wettability of polymers after the treatment. Furthermore, atmospheric plasma can be effectively used to remove surface contamination and to chemically modify different polymer surfaces. The chemical changes, especially oxidation and cross-linking, enhance the surface properties\n of the polymers.","PeriodicalId":43792,"journal":{"name":"Reviews of Adhesion and Adhesives","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2021-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/9781119846703.CH19","citationCount":"19","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reviews of Adhesion and Adhesives","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9781119846703.CH19","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 19
Abstract
This review summarizes the results of cold atmospheric pressure plasma technology application in polymers surface treatment. Attention is given to results of changes in the hydrophilic property of polymer surfaces by incorporation of polar functional groups when exposed to atmospheric
pressure plasma, depending on the time of treatment, applied voltage, gas flow rate, and distance from the surface. We have successfully developed a plasma device that is able to generate cold atmospheric pressure argon plasma of low temperature (20 – 26) ° C downstream using a high-voltage
power source which can be widely used in materials processing. Therefore, a cost-effective system of generating a plasma jet at atmospheric pressure with potential applications has been developed. Cold atmospheric pressure plasma jet (CAPPJ) has shown a lot of applications in recent years
such as in materials processing, surface modification, and biomedical materials processing. CAPPJ has been generated by a high voltage (0-20 kV) and high frequency (20-30 kHz) power supply. The discharge has been characterized by optical and electrical methods. In order to characterize
cold atmospheric pressure argon plasma jet, its electron density, electron temperature, rotational temperature, and vibration temperature have been determined using the power balance method, intensity ratio method, Stark broadening method, and Boltzmann plot method, respectively. The improvement
in hydrophilicity of the cold plasma-treated polymer samples was characterized by contact angle measurements, surface free energy analysis, Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). Contact angle analysis showed that the discharge was effective
in improving the wettability of polymers after the treatment. Furthermore, atmospheric plasma can be effectively used to remove surface contamination and to chemically modify different polymer surfaces. The chemical changes, especially oxidation and cross-linking, enhance the surface properties
of the polymers.
期刊介绍:
With the explosion of research activity and reports, the need for concise and critical reviews of topics of contemporary research interest is manifest. Reviews of Adhesion and Adhesives (RAA) provides in-depth, incisive, illuminating and thought-provoking reviews written by subject matter experts covering all aspects of adhesion science and adhesive technology. Each review will be imbued with the author’s experience so that the reader will be able to assimilate the research in the area discussed easily and will be able to apply it in practice.The journal has relevance to a myriad of industries including textiles, printing, coatings, aerospace, medical, nanotechnology, biotechnology, building and construction, and microelectronics. The topics to be covered include, but not limited to, basic and theoretical aspects of adhesion; modeling of adhesion phenomena; mecha¬nisms of adhesion; surface and interfacial analysis and characterization; unraveling of events at interfaces; characterization of interphases; adhesion of thin films and coatings; adhesion aspects in reinforced composites; formation, characterization and durability of adhesive joints; surface preparation methods; polymer surface modification; biological adhesion; particle adhesion; adhesion of metallized plastics; adhesion of diamond-like films; adhesion pro¬moters; contact angle, wettability· and adhesion; superhydrophobicity and superhydrophilicity. With regard to adhesives, RAA will include, but not limited to, green adhesives; novel and high-performance adhesives; and medical adhesive applications.