Durability of Geopolymer Mortar and Portland Pozzolan Cement (PPC) Mortar against Sulfuric Acid

Ilham Nurhuda, S.T., M.T., Ph.D., Y. A. Priastiwi, N. Nuroji, Variandi Ardidawa, Chazaidhan AlFahd Nizami
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Abstract

The manufacture of cement is often criticized to produce high CO2 emission to environment. Reducing cement in construction is believed to be the solution for better environment. Portland pozzolan cement (PPC) is known as a more environmentally friendly cement which substitutes some portion of cement clinkers with pozzolanic materials such as fly ash. Another material which is considered as green material is Geopolymer. The purpose of this study is to investigate the durability of mortars made of PPC and geopolymer in the corrosive environment. The geopolymer mortar was made of fly ash with 25% white soil substitution, and also 8M NaOH and Na2SiO3 as activators. The corrosive condition was simulated by Sulfuric Acid solution (H2SO4) with a pH of 4. The durability of the two types of mortar was investigated by testing their compressive strength, direct tensile strength, porosity, density and the changes of mass and physical shapes after immersion. The results show that the immersion of the mortars in a solution of pH 4 sulfuric acid does not make any major effects on the performance of the PPC mortar. However, the performance of geopolymer mortar with 25% white soil substitution decreases after being immersed in sulfuric acid solution.
地质聚合物砂浆和波特兰火山灰水泥(PPC)砂浆抗硫酸的耐久性
水泥的生产经常被批评为对环境产生高二氧化碳排放。减少建筑中的水泥被认为是改善环境的解决方案。波特兰火山灰水泥(PPC)是一种更环保的水泥,它用粉煤灰等火山灰材料代替了部分水泥熟料。另一种被认为是绿色材料的材料是地质聚合物。本研究的目的是研究PPC和地质聚合物制成的砂浆在腐蚀环境中的耐久性。地质聚合物砂浆是由粉煤灰和8M NaOH和Na2SiO3作为活化剂制成的,粉煤灰具有25%的白色土壤替代率。用pH为4的硫酸溶液(H2SO4)模拟腐蚀条件。通过测试两种砂浆的抗压强度、直接抗拉强度、孔隙率、密度以及浸泡后质量和物理形状的变化,研究了它们的耐久性。结果表明,砂浆浸泡在pH为4的硫酸溶液中不会对PPC砂浆的性能产生任何重大影响。然而,具有25%白土替代率的地聚合物砂浆在硫酸溶液中浸泡后性能下降。
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