Polyoxometalates in Extraction and Sorption Processes

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Solvent Extraction and Ion Exchange Pub Date : 2021-09-19 DOI:10.1080/07366299.2021.1874107

L. Jelínek, Eva Mištová, M. Kubeil, H. Stephan

引用次数: 2

Abstract

ABSTRACT Polyoxometalates (POMs) represent a fascinating class of inorganic cluster compounds. Due to the almost unlimited possibilities to tailor size, shape and charge of this compound class and to perform various surface functionalization, they are discussed for different applications, especially in the fields of catalysis, material sciences, and biomedicine. In contrast, the systematic study of extraction and sorption properties of POMs has received relatively little attention so far. This review article provides a brief overview of relevant POM structures used for effective and selective phase transfer of metal ions from aqueous into organic media as well as for the development of efficient sorption processes. The use of inorganic-organic POM-based hybrid materials for extraction and sorption processes is also discussed.

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萃取和吸附过程中的多金属氧合物

摘要：多金属氧酸盐（POMs）是一类引人注目的无机簇合物。由于定制这类化合物的尺寸、形状和电荷以及进行各种表面功能化的可能性几乎是无限的，因此讨论了它们的不同应用，特别是在催化、材料科学和生物医学领域。相比之下，到目前为止，对聚甲醛的提取和吸附性能的系统研究相对较少受到关注。这篇综述文章简要概述了用于有效和选择性地将金属离子从水性介质相转移到有机介质中以及开发高效吸附工艺的相关聚甲醛结构。还讨论了无机-有机聚甲醛基杂化材料在萃取和吸附过程中的应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Solvent Extraction and Ion Exchange 化学-化学综合

CiteScore

4.40

自引率

5.00%

发文量

审稿时长

8.4 months

期刊介绍： Solvent Extraction and Ion Exchange is an international journal that publishes original research papers, reviews, and notes that address all aspects of solvent extraction, ion exchange, and closely related methods involving, for example, liquid membranes, extraction chromatography, supercritical fluids, ionic liquids, microfluidics, and adsorption. We welcome submissions that look at: The underlying principles in solvent extraction and ion exchange; Solvent extraction and ion exchange process development; New materials or reagents, their syntheses and properties; Computational methods of molecular design and simulation; Advances in equipment, fluid dynamics, and engineering; Interfacial phenomena, kinetics, and coalescence; Spectroscopic and diffraction analysis of structure and dynamics; Host-guest chemistry, ion receptors, and molecular recognition.