Nickel Hydrogenation Composite Catalysts Modified by Zirconium in Competitive Benzene Hydrogenation: Effect of Modifiers

IF 1.4 Q3 CHEMISTRY, MULTIDISCIPLINARY

Physical Chemistry Research Pub Date : 2020-06-01 DOI:10.22036/PCR.2020.206012.1694

N. Parsafard, M. H. Peyrovi, Mahdi Abdali Hajiabadi

引用次数: 1

Abstract

A co-impregnation method was applied to the Ni/Zr-HMS/HZSM-5 catalyst (with various amounts of zirconium) during the hydrogenation of benzene. The physicochemical properties of the prepared nickel catalyst were characterized using X - ray diffraction, X - ray fluorescence, Fourier transform infrared spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy, temperature-programmed desorption of ammonia, H2 chemisorption, N2 adsorption - desorption, and thermogravimetric analysis. The catalytic performance was assessed on a fixed-bed reactor (reaction temperature between 130 °C and 190 °C). The results indicated that the nickel catalyst with Si/Zr = 35 exhibited better catalytic performance and stability than others, so providing a better selectivity in long-term performance.

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锆改性苯竞争加氢镍加氢复合催化剂：改性剂的影响

采用共浸渍法对不同锆用量的Ni/Zr-HMS/HZSM-5催化剂进行了苯加氢反应。采用X射线衍射、X射线荧光、傅里叶变换红外光谱、紫外-可见漫反射光谱、程序升温解吸氨、H2化学吸附、N2吸附-解吸、热重分析等方法对制备的镍催化剂的理化性质进行了表征。在固定床反应器(反应温度130 ~ 190℃)上评价了催化性能。结果表明，Si/Zr = 35的镍催化剂表现出较好的催化性能和稳定性，在长期性能上具有较好的选择性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Physical Chemistry Research CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

2.70

自引率

8.30%

发文量

期刊介绍： The motivation for this new journal is the tremendous increasing of useful articles in the field of Physical Chemistry and the related subjects in recent years, and the need of communication between Physical Chemists, Physicists and Biophysicists. We attempt to establish this fruitful communication and quick publication. High quality original papers in English dealing with experimental, theoretical and applied research related to physics and chemistry are welcomed. This journal accepts your report for publication as a regular article, review, and Letter. Review articles discussing specific areas of physical chemistry of current chemical or physical importance are also published. Subjects of Interest: Thermodynamics, Statistical Mechanics, Statistical Thermodynamics, Molecular Spectroscopy, Quantum Chemistry, Computational Chemistry, Physical Chemistry of Life Sciences, Surface Chemistry, Catalysis, Physical Chemistry of Electrochemistry, Kinetics, Nanochemistry and Nanophysics, Liquid Crystals, Ionic Liquid, Photochemistry, Experimental article of Physical chemistry. Mathematical Chemistry.