{"title":"Pertoldite, trigonal GeO2, the germanium analog of α-quartz: a new mineral from Radvanice, Czech Republic","authors":"Z. V., Š. R., Laufek F., S. J., H. J.","doi":"10.3190/jgeosci.355","DOIUrl":null,"url":null,"abstract":"The new mineral pertoldite was found in a burning waste dump of abandoned Kateřina colliery at Radvanice near Trutnov, Hradec Králové Department, Czech Republic. The dump fire started spontaneously before 1980 and no anthropogenic material was deposited there. The determination of pertoldite as a natural analogue of synthetic trigonal α-GeO 2 is based on its chemical composition, X-ray powder diffraction data, and Raman spectroscopy. Pertoldite occurs as white to brownish aggregates resembling cotton tufts, up to 1 mm in size, composed of acicular crystals up to ~1 μm thick and up to 1 mm in length. Individual crystals are distorted, resembling textile fibers. Pertoldite was formed by direct crystallization from hot (400–500 °C) gasses containing Cl and F as transporting agents at a depth of 40–60 cm under the surface of a burning coal mine dump. It nucleated as a thin, delicate crust on a chip of siltstone together with multi-component aggregates of galena, stibnite, bismuthian antimony, greenockite, and bismuth. The ideal formula of pertoldite, GeO 2 , requires 100 wt. % GeO 2 . Germanium is partially substituted by silica (2.33–5.67 wt. % SiO 2 ), the extent of Ge 1 Si –1 substitution is limited to 0.03–0.09 apfu Si, and the empirical formula ranges between (Ge 0.91-0.97 Si 0.03-0.09 ) Σ1.00 O 2 . Pertoldite is trigonal, P 3 1 21 or P 3 2 21, a = 4.980(5) Å, c = 5.644(4) Å, with V = 121.2(2) Å 3 and Z = 3. The strongest reflections of the powder X-ray diffraction pattern [d (Å)/I ( hkl )] are: 4.315/44(100), 3.425/100(101,011), 2.490/31(110), 2.360/41(012,102), 1.867/31(112), 1.4179/31(023,203), 1.4124/37 (122,212). The crystal structure of pertoldite is based on corner-sharing [GeO 4 ] tetrahedra forming a three-dimensional network similar to that of α-quartz. Pertoldite is named after Zdeněk Pertold (1933–2020), professor of economic geology at the Faculty of Sciences, Charles University in Prague. The mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (number 2021-074) and the holotype specimen is deposited in the collections in the Department of Mineralogy and Petrology, National Museum in Prague, under the catalogue number P1P 31/2021.","PeriodicalId":15957,"journal":{"name":"Journal of Geosciences","volume":null,"pages":null},"PeriodicalIF":1.1000,"publicationDate":"2022-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geosciences","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.3190/jgeosci.355","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 1
Abstract
The new mineral pertoldite was found in a burning waste dump of abandoned Kateřina colliery at Radvanice near Trutnov, Hradec Králové Department, Czech Republic. The dump fire started spontaneously before 1980 and no anthropogenic material was deposited there. The determination of pertoldite as a natural analogue of synthetic trigonal α-GeO 2 is based on its chemical composition, X-ray powder diffraction data, and Raman spectroscopy. Pertoldite occurs as white to brownish aggregates resembling cotton tufts, up to 1 mm in size, composed of acicular crystals up to ~1 μm thick and up to 1 mm in length. Individual crystals are distorted, resembling textile fibers. Pertoldite was formed by direct crystallization from hot (400–500 °C) gasses containing Cl and F as transporting agents at a depth of 40–60 cm under the surface of a burning coal mine dump. It nucleated as a thin, delicate crust on a chip of siltstone together with multi-component aggregates of galena, stibnite, bismuthian antimony, greenockite, and bismuth. The ideal formula of pertoldite, GeO 2 , requires 100 wt. % GeO 2 . Germanium is partially substituted by silica (2.33–5.67 wt. % SiO 2 ), the extent of Ge 1 Si –1 substitution is limited to 0.03–0.09 apfu Si, and the empirical formula ranges between (Ge 0.91-0.97 Si 0.03-0.09 ) Σ1.00 O 2 . Pertoldite is trigonal, P 3 1 21 or P 3 2 21, a = 4.980(5) Å, c = 5.644(4) Å, with V = 121.2(2) Å 3 and Z = 3. The strongest reflections of the powder X-ray diffraction pattern [d (Å)/I ( hkl )] are: 4.315/44(100), 3.425/100(101,011), 2.490/31(110), 2.360/41(012,102), 1.867/31(112), 1.4179/31(023,203), 1.4124/37 (122,212). The crystal structure of pertoldite is based on corner-sharing [GeO 4 ] tetrahedra forming a three-dimensional network similar to that of α-quartz. Pertoldite is named after Zdeněk Pertold (1933–2020), professor of economic geology at the Faculty of Sciences, Charles University in Prague. The mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (number 2021-074) and the holotype specimen is deposited in the collections in the Department of Mineralogy and Petrology, National Museum in Prague, under the catalogue number P1P 31/2021.
期刊介绍:
The Journal of Geosciences is an international peer-reviewed journal published by the Czech Geological Society with support from the Czech Geological Survey. It accepts high-quality original research or review papers dealing with all aspects of the nature and origin of igneous and metamorphic rocks. The Journal focuses, mainly but not exclusively, on:
-Process-oriented regional studies of igneous and metamorphic complexes-
Research in structural geology and tectonics-
Igneous and metamorphic petrology-
Mineral chemistry and mineralogy-
Major- and trace-element geochemistry, isotope geochemistry-
Dating igneous activity and metamorphic events-
Experimental petrology and mineralogy-
Theoretical models of igneous and metamorphic processes-
Mineralizing processes and mineral deposits.
All the papers are written in English, even though they may be accompanied by an additional Czech abstract. Each contribution is a subject to peer review by at least two independent reviewers, typically at least one from abroad. The Journal appears 2 to 4 times a year. Formally it is divided in annual volumes, each of them including 4 issues.