Salt dissolution tectonism and origin of lacustrine carbonate beds: Mn-Fe-calcite and Mn-siderite micro-spherulite fabrics of the Lower Cretaceous McMurray Formation, Athabasca Oil Sands deposit, western Canada

Abstract

Several lacustrine carbonate beds, each a metre-thick interval of densely packed Mn-rich sideritic micro-spherulites or Mn-rich ferroan calcite micro-spherulites, are recorded for the first time within strata of the Lower Cretaceous McMurray Formation of the northern Athabasca Oil Sands deposit, western Canada. A lower McMurray lacustrine carbonate deposit is characterised by a metre-thick bed fabric of Mn-rich siderite micro-spherulites. The middle and upper interval McMurray beds developed fabrics of Mn²⁺-rich ferroan calcite micro-spherulites. These carbonate beds represent saline lacustrine depositional environments that resulted from the lake bottom sediments ingressed from below by Mn²⁺-Fe²⁺-rich carbonate-saturated brines. These up-section migrations of Devonian formation water were sourced from dissolution trends developed in limestone and halite-anhydrite beds of the underlying Devonian Prairie Evaporite during Cordilleran deformation of the Alberta Basin foreland. These brines ascended to the overlying McMurray Formation sediments along dissolution-collapse structures such as breccia pipes, sinkholes and margins of differentially subsided Upper Devonian fault blocks. The up-section migration of a sulphate-saturated Fe²⁺ and Mn²⁺-rich brine resulted in the ingress of a lower McMurray lacustrine bottom sediment at a site associated with the development of a peat mire terrain. Microbial redox of the lake bottom sediment resulted in a carbonate bed of micro-spherulitic fabrics of Mn-rich siderite interwoven with pyrite laminae. Subsequent salt dissolution events and up-section migrations of Devonian brine during deposition of the middle and upper McMurray intervals resulted in similar carbonate-saturated but sulphate-poor chemistry. These saline flows also ingressed lacustrine bottom sediments below, and resulted in limestone beds of densely packed spherulitic fabrics of Mn-ferroan calcite, not siderite. These deposits provide insight into largely unknown dispositions of voluminous brine resulting from salt dissolution trends below the Athabasca Oil Sands and further our understanding of controversial McMurray depositional processes.