{"title":"Adsorptive Removal of Phosphate From Wastewater Using Ethiopian Rift Pumice: Batch Experiment","authors":"Yohannis Fetene, T. Addis","doi":"10.1177/1178622120969658","DOIUrl":null,"url":null,"abstract":"Phosphorous from municipal and industrial wastewater is the main cause of eutrophication of rivers and lakes, because effluent quality from conventional secondary wastewater treatment plants does not meet the discharge standard that demands further treatment. Therefore, we investigated pumice as a potential low-cost adsorbent for the tertiary treatment of phosphate from municipal wastewater. The phosphate adsorption process reached equilibrium after 60 minutes contact time and achieved a removal efficiency of 94.4% ± 0.7% for an adsorbent dose of 10 g/L in 3 mg/L phosphate solution. The highest phosphate removal was recorded at pH 7. The experimental data best fitted with the Redlich-Peterson isotherm and the pseudo-second-order kinetic models. The coexisting anions decreased phosphate adsorption in the order of mixture >SO42– > HCO3− > NO3− > Cl− > CO3−. Pumice removed 95% ± 0.2% of phosphate from effluents of the secondary treatment unit of a municipal wastewater treatment plant. Furthermore, effective regeneration of saturated pumice was possible with a 0.2 M NaOH solution. Therefore, pumice could be a technically workable low-cost reusable adsorbent for phosphate removal from wastewater as a tertiary treatment to curb eutrophication of surface waters. However, further column adsorption study is recommended for a continuous flow system to optimize process design variables and scale up for field applications.","PeriodicalId":44801,"journal":{"name":"Air Soil and Water Research","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2020-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/1178622120969658","citationCount":"9","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Air Soil and Water Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1177/1178622120969658","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 9
Abstract
Phosphorous from municipal and industrial wastewater is the main cause of eutrophication of rivers and lakes, because effluent quality from conventional secondary wastewater treatment plants does not meet the discharge standard that demands further treatment. Therefore, we investigated pumice as a potential low-cost adsorbent for the tertiary treatment of phosphate from municipal wastewater. The phosphate adsorption process reached equilibrium after 60 minutes contact time and achieved a removal efficiency of 94.4% ± 0.7% for an adsorbent dose of 10 g/L in 3 mg/L phosphate solution. The highest phosphate removal was recorded at pH 7. The experimental data best fitted with the Redlich-Peterson isotherm and the pseudo-second-order kinetic models. The coexisting anions decreased phosphate adsorption in the order of mixture >SO42– > HCO3− > NO3− > Cl− > CO3−. Pumice removed 95% ± 0.2% of phosphate from effluents of the secondary treatment unit of a municipal wastewater treatment plant. Furthermore, effective regeneration of saturated pumice was possible with a 0.2 M NaOH solution. Therefore, pumice could be a technically workable low-cost reusable adsorbent for phosphate removal from wastewater as a tertiary treatment to curb eutrophication of surface waters. However, further column adsorption study is recommended for a continuous flow system to optimize process design variables and scale up for field applications.
期刊介绍:
Air, Soil & Water Research is an open access, peer reviewed international journal covering all areas of research into soil, air and water. The journal looks at each aspect individually, as well as how they interact, with each other and different components of the environment. This includes properties (including physical, chemical, biochemical and biological), analysis, microbiology, chemicals and pollution, consequences for plants and crops, soil hydrology, changes and consequences of change, social issues, and more. The journal welcomes readerships from all fields, but hopes to be particularly profitable to analytical and water chemists and geologists as well as chemical, environmental, petrochemical, water treatment, geophysics and geological engineers. The journal has a multi-disciplinary approach and includes research, results, theory, models, analysis, applications and reviews. Work in lab or field is applicable. Of particular interest are manuscripts relating to environmental concerns. Other possible topics include, but are not limited to: Properties and analysis covering all areas of research into soil, air and water individually as well as how they interact with each other and different components of the environment Soil hydrology and microbiology Changes and consequences of environmental change, chemicals and pollution.