Kinetic Study of Transesterification Reaction of Edible Oil Using Heterogenous Catalyst

Haider Aljendeel, E. Borhan, M. Al-Ani
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Abstract

   AlPO4 solid acid catalyst was prepared in order to use it in transesterification reaction of edible oil after supporting it with tungsten oxide. The maximum conversion of edible oil was obtained 78.78% at catalyst concentration (5gm.), temperature 70°Ϲ, 30/1 methanol/edible oil molar ratio, and time 5hr. The study of kinetics of the transesterification reaction of edible oil indicates that the reaction has an order of 3/2, while the value of activation energy for  transesterification reaction is 51.367 kJ/mole and frequency factor equal 26219.13(L/ mol.minute).
多相催化剂催化食用油酯交换反应动力学研究
以氧化钨为载体,制备了用于食用油酯交换反应的AlPO4固体酸催化剂。在催化剂浓度为5gm、温度为70°Ϲ、甲醇/食用油摩尔比为30/1、反应时间为5hr的条件下,食用油的最大转化率为78.78%。对食用油酯交换反应的动力学研究表明,该反应为3/2级,酯交换反应的活化能为51.367 kJ/mol,频率因子为26219.13(L/ mol.min)。
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