Trace-element chemistry of barren and ore-bearing quartz of selected Au, Au-Ag and Sb-Au deposits from the Bohemian Massif

IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS
K. Pacak, J. Zachariáš, L. Strnad
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引用次数: 11

Abstract

The trace-element contents in gold-bearing and barren quartz veins from eight Au, Au–Ag and Sb–Au Variscan deposits in the Bohemian Massif have been determined in situ in order to evaluate the differences between the various types of gold deposits and discuss trace-element variations in the successive generations of quartz veins. The variability of Ti, Al, Ge, Li and Sb abundances obtained by Laser-Ablation Inductively-Coupled Plasma Mass Spectrometry (LA-ICP-MS) roughly correlates with the origin and the temperature of the mineralizing fluids. The Al content ranges up to 4020 ppm (median value 230 ppm), while the Li content is generally low (< 4 ppm). The elevated Sb content (30–360 ppm Sb) is only related to quartz that immediately preceded deposition of Sb-rich phases. The titanium content of the ore-bearing vein quartz follows bimodal distribution: gold deposits with assumed higher temperature (> 450 °C) formation exhibit higher median values (~10 ppm Ti) than medium-to-low (< 300 °C) temperature deposits (~2 ppm Ti). A statistically significant threshold value (8 ppm Ti) has been recognized as an empirical tool for discriminating between them. In terms of the Ti and Al contents, the studied Bohemian gold deposits fall within and in between fields of orogenic gold and porphyry deposit types.
波西米亚地块部分Au、Au- ag和Sb-Au矿床贫矿石英微量元素化学特征
本文对波希米亚地块8个金、金、银、锑金Variscan矿床的含金和贫瘠石英脉中的微量元素含量进行了原位测定,以评价各类型金矿床之间的差异,并讨论了历代石英脉中微量元素的变化。激光烧蚀电感耦合等离子体质谱法(LA-ICP-MS)测得的Ti、Al、Ge、Li和Sb丰度的变化与矿化流体的来源和温度大致相关。Al含量最高可达4020 ppm(中值230 ppm),而Li含量普遍较低(< 4 ppm)。Sb含量升高(30-360 ppm Sb)仅与富Sb相沉积前的石英有关。含矿脉石英的钛含量呈双峰分布:假设温度较高(bb0 ~ 450℃)的金矿床的Ti中值(~10 ppm)高于中低温(< 300℃)的金矿床(~2 ppm)。统计上显著的阈值(8 ppm Ti)已被认为是区分它们的经验工具。从钛和铝的含量上看,波西米亚金矿属于造山带型金矿和斑岩型金矿的范畴或介于两者之间。
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来源期刊
Journal of Geosciences
Journal of Geosciences GEOSCIENCES, MULTIDISCIPLINARY-MINERALOGY
CiteScore
2.30
自引率
7.10%
发文量
15
审稿时长
>12 weeks
期刊介绍: The Journal of Geosciences is an international peer-reviewed journal published by the Czech Geological Society with support from the Czech Geological Survey. It accepts high-quality original research or review papers dealing with all aspects of the nature and origin of igneous and metamorphic rocks. The Journal focuses, mainly but not exclusively, on: -Process-oriented regional studies of igneous and metamorphic complexes- Research in structural geology and tectonics- Igneous and metamorphic petrology- Mineral chemistry and mineralogy- Major- and trace-element geochemistry, isotope geochemistry- Dating igneous activity and metamorphic events- Experimental petrology and mineralogy- Theoretical models of igneous and metamorphic processes- Mineralizing processes and mineral deposits. All the papers are written in English, even though they may be accompanied by an additional Czech abstract. Each contribution is a subject to peer review by at least two independent reviewers, typically at least one from abroad. The Journal appears 2 to 4 times a year. Formally it is divided in annual volumes, each of them including 4 issues.
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