Quantitative model for silicon-acrylate mixtures

Q3 Engineering
K. Sladká
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引用次数: 0

Abstract

: Protection of surface layers of building materials are very important in construction industry. Plasters, which are used as a cover layer of load bearing structure, must resist to the adverse natural conditions, corrosion or mechanical damage. As the surface treatment there are used coatings which must require material and physical characteristics and help to resist to the material degradation. This article is focused on silicon-acrylate coatings. Silicons (polysiloxanes) are very resistant and expensive. Acrylates are cheaper and less resistant than polsiloxanes. The coating samples were measured in the ATR module in the infrared spectrometer. The advantage of this method is that the sample doesn´t need to be modified and the measurement is quite cheap. As a result, the mathematical model for quantitative analysis was created – the quadratic dependence of carbonyl peak area on the concentration of acrylate. Indirectly, the polysiloxane concentration can be calculated. In the reality the calculation of polysiloxane concentration can be the problem because of additives. The conditions of the measurement were specified and the statistical deviation was determined to be 4.6 %.
硅丙烯酸酯混合物的定量模型
在建筑行业中,建筑材料表层的保护是非常重要的。石膏作为承重结构的覆盖层,必须能抵抗恶劣的自然条件、腐蚀或机械损伤。作为表面处理,使用的涂层必须要求材料和物理特性,并有助于抵抗材料降解。本文的重点是硅-丙烯酸酯涂料。硅(聚硅氧烷)非常耐腐蚀且价格昂贵。丙烯酸酯比聚硅氧烷更便宜,耐腐蚀性也更差。涂层样品在红外光谱仪的ATR模块中进行测量。这种方法的优点是样品不需要修改,而且测量成本很低。由此建立了定量分析的数学模型——羰基峰面积与丙烯酸酯浓度的二次依赖关系。间接地计算聚硅氧烷的浓度。在实际中,由于添加剂的存在,聚硅氧烷浓度的计算会出现问题。规定了测定条件,确定了统计偏差为4.6%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Gong Cheng Li Xue/Engineering Mechanics
Gong Cheng Li Xue/Engineering Mechanics Engineering-Mechanical Engineering
CiteScore
2.80
自引率
0.00%
发文量
10549
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